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Synthesis 2012(1): 99-103  
DOI: 10.1055/s-0031-1289630
PAPER
© Georg Thieme Verlag Stuttgart ˙ New York

An Effective Catalytic α-Phosphoryloxylation of Ketones with Iodobenzene

Ye Pua, Liumian Gaob, Huijun Liua, Jie Yan*a
a College of Chemical Engineering and Materials Science, Zhejiang University of Technology, Hangzhou 310032, P. R. of China
Fax: +86(571)88320238; e-Mail: jieyan87@zjut.edu.cn;
b Research Institute of Nanjing Chemical Industrial Group, Nanjing 210048, P. R. of China
Further Information

Publication History

Received 23 August 2011
Publication Date:
30 November 2011 (online)

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Abstract

An effective catalytic method for α-phosphoryloxylation of ketones is reported. When ketones were reacted with phosphates in the presence of iodobenzene as the recyclable catalyst and m-chloroperbenzoic acid as the terminal oxidant in acetonitrile at room temperature, the α-phosphoryloxylation of ketones took place easily and the corresponding keto phosphates were obtained in moderate to good yields.

Key words

α-phosphoryloxylation - keto phosphate - hypervalent iodine reagent - catalytic oxidation

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