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DOI: 10.1055/s-0028-1088371
Three-Membered Ring Sesquiterpenoids with NGF-Potentiating Activity from the Roots of Valeriana fauriei
Planta Med 2006, 72 (4): 373 – 375Publication History
Publication Date:
17 November 2008 (online)
The structures of compounds 1∼3 reported in this paper,Planta Medica, 2006, 72: 373 – 375 , were incorrect. In this erratum, we report the corrected structures of compounds 1∼3 (Fig. [1]). Among them, compound 1 is isobicyclogermacrenal previously reported in the literature [1], while compounds 2 and 3 are new sesquiterpenoids. Their NMR data are assigned correctly in Table [1]1 based on 2D NMR spectra and the comparison of the spectral data with those reported in the literature for 1 [1].
1 Tucker DJ, Southwell IA, Lowe RF, Russell MF, Brerton IM. 1H and 13C-NMR assignments for the sesquiterpene aldehydes, lepidozenal and isobicyclogermacrenal, from Eucalyptus dawsonii. Magnetic in Chemistry 2007; 45: 1081 – 3
Position | 1 | 2 | 3 | |||
δH a | δC | δH a | δC | |||
1 | 5.00 dd (11.0/5.5) | 124.3 | 4.84 dd (11.0/5.5) | 126.5 | 5.09 dd (11.0/5.5) | 129.6 |
2 | 2.07 m 2.16 m | 27.7 | 1.82 m 1.90 m | 27.7 | 1.95 m 2.05 m | 27.2 |
3 | 2.74 m 1.94 m | 23.5 | 2.44 d (12.4) 1.66 m | 23.2 | 2.57 m 1.76 m | 22.7 |
4 | 142.9 | 142.3 | 142.0 | |||
5 | 6.24 d (9.5) | 156.1 | 6.06 d (9.7) | 156.7 | 6.14 d (9.5) | 155.2 |
6 | 1.43 t (9.5/9.5) | 29.8 | 1.13 dd (9.7/8.9) | 29.7 | 1.22 t (9.5/9.5) | 28.9 |
7 | 0.90 m | 38.2 | 0.65 m | 37.2 | 0.71 m | 36.4 |
8 | 0.81 m 1.78 m | 23.4 | 0.56 m 1.52 m | 23.6 | 0.64 m 1.63 m | 23.2 |
9 | 1.96 m 2.13 m | 39.8 | 1.50 m 2.30 m | 34.3 | 1.66 m 2.13 m | 34.5 |
10 | 134.4 | 137.8 | 132.4 | |||
11 | 21.2 | 21.0 | 20.2 | |||
12 | 1.13 s | 15.7 | 0.88 s | 15.7 | 0.95 s | 15.2 |
13 | 1.10 s | 28.5 | 0.88 s | 28.4 | 0.93 s | 27.9 |
14 | 1.19 s | 17.2 | 3.38 d (11.7) 3.10 d (11.7) | 58.1 | 3.89 s | 60.2 |
15 | 9.20 s | 194.3 | 8.89 s | 194.2 | 9.03 s | 192.9 |
OCOCH3 | 169.9 | |||||
OCOCH 3 | 1.74 s | 20.4 |