Synfacts

Rubrik: Organo- and Biocatalysis

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Ausgabe 01/2020

Excited-State Electron Transfer Enables Organocatalytic Deracemization of Ureas
Peptide-Catalyzed Enantioselective Desymmetrization of Pyridines
Enzyme-Catalyzed Asymmetric, Intramolecular C(sp3)–H Amination
NHC-Catalyzed N,O-Acetal Formation from Heteroarenes and Ketones
Asymmetric Synthesis of Chiral Esters by a Catalytic Wolff Rearrangement
Regiocomplementary Chlorination Enabled by Evolved Aliphatic Halogenases
Formal α-Arylation of Ketones Enabled by Vinyl Cation Stabilization
Polyene Cyclizations Through Iminium Ion Activation
Quinone-Mediated Formal α-Umpolung of Aldehydes
Antibodies as Highly Substrate-Selective Catalysts: Choosing the Right Hapten Can Do The Trick
All PDFs of this category

Ausgabe 12/2019

Cinchona Primary Amine-Catalyzed Asymmetric Epoxidation Towards Dithiodiketopiperazines
A Multifunctional Dimeric Organocatalyst Enables Efficient Peptide Bond Formation
Hydrazine-Catalyzed Ring-Closing Carbonyl–Olefin Metathesis for the Synthesis of 2H-Chromenes
Amine-Catalyzed Enantioselective Synthesis of Cyclic β-Amino Aldehydes
Bringing the Inert Si–Si Bond Back to Life: Disilylation of Nonactivated Olefins with Hexamethyldisilane
Construction of Quaternary Carbon Centers by Lewis Acid Catalyzed Transfer Hydromethallylation
Utilization of a Phosphetane Oxide for Catalytic Wittig-Reactions
Organocatalysis Meets Hydrogen Storage: Efficient Dehydrogenation of Ammonia-Borane
Combining Photoredox and Biocatalysis for a General Enantioselective Benzylic Hydroxylation
Carbonyl Catalysis: Acetaldehyde-Catalyzed Synthesis of Oxamide by Hydrolysis of Cyanogen
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Ausgabe 11/2019

A Newly Designed Catalyst for Additive-Free Mitsunobu Reactions
Brønsted Acid Catalyzed Asymmetric House–Meinwald Rearrangement of p-Hydroxyphenyl Epoxides
Asymmetric Functionalization of C(sp3)–H Bonds in 2-Alkylindoles
NHC-Catalyzed Carboacylation of Alkenes
Lewis Base Catalyzed Enantioselective Sulfenoamination of Olefins
Asymmetric NHC-Catalyzed Rauhut–Currier Reaction of Weakly Electrophilic Bisenoates
Phosphenium Ion Catalyzed Enantioselective Reduction of Cyclic Imines
Asymmetric Phosphoric Acid Catalyzed Multi-Component Synthesis of Axially Chiral N-Arylindoles
N-Heterocyclic Carbene Catalyzed Stetter Reaction of Cyclic Enones
Organometallic Organocatalysts
All PDFs of this category

Ausgabe 10/2019

Sulfenylation/Semipinacol Reaction of Di- and Trisubstituted Allylic Alcohols
Dehydrative Annulation of Amines with Carboxylic Acids via PIII/PV Catalysis
Stereoselective Radical Cyclization by Photoexcited Flavoenzymes
Organocatalytic Aldehyde Olefination: Synthesis of α,β-Disubstituted Acrylates
Benzylic Photocarboxylation through C–H Bond Photoactivation
Radical Chain Reaction Catalyzed by Organic Super Electron Donors
Electrophotoredox Coupling Between Arenes and Nitrogen Heteroaromatics
Coordinatively Saturated Phosphorus(V) Species Initiates Silylium Catalysis
Asymmetric Lewis Base-Catalyzed Sulfenoacetalization of Alkenals
Organocatalytic Synthesis of γ-Butyrolactones
The Steglich Esterification
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Ausgabe 09/2019

(5+1) Annulations through Double Umpolung of Conjugate Acceptors
Photoredox [4+2] Annulation to Construct Substituted Benzene Rings
Catalytic Friedel–Crafts Conjugate Addition/Enantioselective Protonation
Directed Evolution Enables Direct C(sp3)–H Fluoroalkylation
Positioning-Group-Enabled Biocatalytic Oxidative Dearomatization
Protein Engineering Enables Stereodivergent Cyclopropanation
Visible-Light-Induced Organocatalytic Borylation of Aryl Chlorides
Organocatalytic Biomimetic Synthesis of 4-Arylquinolizidine Alkaloids
Atroposelective Cyclodehydration Enabled by Disparate Catalytic Scaffolds
The Stetter Reaction
Carbon Dioxide-Catalyzed Michael-Type Cyanation of Coumarin Derivatives
All PDFs of this category

Ausgabe 08/2019

Enzyme-Catalyzed Site-Selective C–H Amidation
Chiral Phosphine Catalyzed Asymmetric Staudinger–aza-Wittig Reaction
Photochemical Organocatalytic Borylation of Alkyl Halides and Sulfonates
Benzothiophene-Catalyzed Oxidative Coupling of 2-Naphthols
Benziodoxole-Catalyzed Anti-Markovnikov Hydroazidation of Olefins
Organocatalytic Enantioselective Dichlorination of Cyclic Styrenes
[4+2] Cycloaddition via NHC-Bound Aza-ortho-Quinone Methides
Diazaphospholene-Catalyzed Reductive Ireland–Claisen Rearrangement
Asymmetric Catalytic Transannular Morita–Baylis–Hillman Reaction
A Bifunctional Catalyst Permits Atroposelective Aromatization
Enantioselective Protonation of Disilyl Ketene Acetals with Water or Methanol
Thiazolium Salt Catalyzed Asymmetric Benzoin Reaction
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Ausgabe 07/2019

Phosphine/Iodide-Based Photoredox-Catalyzed Decarboxylative Alkylations
Chiral Brønsted Acid-Catalyzed Direct Reductive Amination with Silanes
Phthalidyl Ester Prodrugs by Catalytic Asymmetric Acetalization of Carboxylic Acids
Synthesis of Tricyclic Scaffolds through Photochemical and Prins–Ritter Reactions
Machine Learning-Assisted Directed Evolution of Proteins
An Enzyme-Catalyzed Inverse-Electron-Demand Diels–Alder Reaction
Regioselective Vinylogous Aldol Condensation of α,β-Unsaturated Aldehydes
Toward Chiral 1,4-Enynes: Asymmetric Alkenylation of Propargyl Alcohols
Catalytic Asymmetric Alkylations via Phase-Transfer Catalysis
Organocatalytic Baeyer–Villiger Oxidation for the Synthesis of Prostaglandins
Cyclization of 2-Methylene-2H-indols with ortho-Quinone Methides Generated In Situ
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Ausgabe 06/2019

Valorization of a Saturated Fatty Acid to Enantioenriched (S)-δ-Decalactone
Organocatalytic Asymmetric Hydroamination of Allenes and Dienes
Biosynthesis of Streptoseomycin Involves a [6+4] Cycloaddition
Amination of Sugars and Sugar-Derived Tetrahydrofurans with Transaminases
Organocatalytic Synthesis of Unsymmetrical 1,2,4,5-Tetrazines
Halogen Bond Catalyzed Strain-Release Glycosylation
Biocatalytic Synthesis of d-Tryptophans from Indoles
Enantioselective Radical Addition to Vinylpyridines by Photoredox Catalysis
The Shi Epoxidation
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Ausgabe 05/2019

N-Heterocyclic Carbene Catalyzed Alkylation of Aromatic Aldehydes
Acid-Catalyzed Intramolecular Hydroindolation of cis-Methindolylstyrenes
Hydrogen-Bonding Phase-Transfer Catalysis toward β-Fluoroamines
Chiral Brønsted Acid Catalyzed Asymmetric Oxidation of Sulfenamides
Enantioselective Aminocatalytic Heterocycloadditions
Asymmetric Organocatalytic Oxidative Coupling of Indoles with Aldehydes
Stereospecific Biocatalytic Friedel–Crafts Alkylation of Resorcinols
Asymmetric Countercation Directed Catalysis of an SN2X Reaction
Enzymatic Carboxylation of 2-Furoic Acid to 2,5-Furandicarboxylic Acid
The Asymmetric Nazarov Cyclization of Simple Divinyl Ketones
Asymmetric Countercation Directed Catalytic Resolution of BINOLs
Cinchona Alkaloids in Organic Catalysis
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Ausgabe 04/2019

Application of Chemoinformatics in Asymmetric Catalysis
Asymmetric Enzymatic Aminohydroxylation of Styrenyl Olefins
Directed Evolution Permits Heme-Protein-Catalyzed sp3-C–H Alkylation
Asymmetric Synthesis of Trifluoromethylated Spirooxindole Lactones
Asymmetric Synthesis of All-Carbon Spirocycles by a Stetter/Aldol Cascade
Chiral Bifunctional Phase-Transfer Catalysts for Asymmetric Aminations
Electrophilic Sulfenylation of Indoles by PIII/PV=O Catalysis
NHC-Catalyzed Aza-Stetter Reaction of Aldimines To Give 3-Methylenechromanones
Aminoxyl-Catalyzed Electrochemical Diazidation of Alkenes
The Knoevenagel Condensation
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Ausgabe 03/2019

Catalytic Deracemization of Allenes
Iodine-Catalyzed Carbonyl–Olefin Metathesis
The Morita–Baylis–Hillman Reaction
Asymmetric Synthesis of 2-Pyrazolines by a Catalytic Aza-Michael Addition
Metal-Free Transfer Hydroiodination of Allenes and Alkynes
Chiral Phosphoric Acid Catalyzed [4+2] Cycloaddition toward Griffipavixanthone
Enantioselective Dearomatization of Pyrylium Derivatives
Chiral Phosphoric Acid Catalyzed Allylic Dearomatization of α- and β-Naphthols
Enantioselective Construction of Vicinal Diaxial Styrenes and Multiaxis Systems
Peroxygenase-Catalyzed Hydroxylation of Ethylbenzene
Baeyer–Villiger Oxidation Catalyzed by a Peptide-Based Phosphoric Acid
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Ausgabe 02/2019

Catalytic Asymmetric Mukaiyama Aldol Reaction of Acetaldehyde Enolates
Enantioselective Four-Atom Ring Expansion of Cyclobutanones
Catalytic Asymmetric α-Hydroxylation of Cyclic α-Branched Ketones
Brønsted Acid Catalyzed Diastereoselective [4+3] Cycloaddition
Photoredox-Catalyzed Multicomponent Alkyl Radical Carbonylation
Chiral Sulfides as Catalysts for Asymmetric Electrophilic Olefin Chlorination
A Double Umpolung Reaction to Synthesize β-Amino Amides
Photoredox-Catalyzed Difunctionalization of Olefins with Carbon Dioxide
Enantioselective Photoorganocatalytic Synthesis of 1,4-Dicarbonyl Compounds
The Hajos–Parrish–Eder–Sauer–Wiechert Reaction
All PDFs of this category

Ausgabe 01/2019

Chiral Lewis Base Catalyzed Aldol Reaction of Unprotected Carboxylic Acids
Stereodynamic Redox-Interconversion Network of Hybrid Dihydrobenzofurans
The Dawn of Directed Evolution
Bienzymatic Oxidative Lactamization of Aliphatic Amino Alcohols
Carbon–Fluorine Bond Cleavage by an Engineered Enzyme
Reductive C–N Cross-Coupling of Nitroarenes by PIII/PV=O Catalysis
Cinchona-Amine-Catalyzed Stepwise [6+4] Cycloadditions
Catalytic Diels–Alder Reaction of α,β-Unsaturated Methyl Esters
Organocatalytic Synthesis of γ,γ-Disubstituted Butenolides
From CO2 to Cyclic Carbonates: Organocatalysts Do It under Mild Conditions
Improved Efficiency with New Cinchona-Based Catalysts in Umpolung Reactions
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Ausgabe 12/2018

Asymmetric Phosphoric Acid Catalyzed Four-Component Ugi Reaction
Photoredox-Catalyzed Decarboxylative Radical Cyclization Cascade
Asymmetric Organocatalytic Vicinal Difluorination of Styrenes
Asymmetric Enzymatic Hydration of Nonactivated Olefins
Asymmetric Oxidative Coupling of Carboxylic Acids to α-Branched Aldehydes
Synthesis of Axially Chiral Anilides by Atroposelective Allylic Alkylation
N-Heterocyclic Carbene Catalyzed Umpolung Acylation in Fullerene Chemistry
Functionalization of Enamides Catalyzed by a Chiral Phosphoric Acid
Application of Nitrones for the Asymmetric Synthesis of Substituted Piperidines
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Ausgabe 11/2018

Stereodivergent Synthesis of 2,3-Disubstituted 1,4-Dicarbonyls
Benzo[c]cinnoline-Catalyzed Oxidation of Alkyl Halides to Aldehydes
Photoorganocatalytic Radical Reaction of Cinnamaldehydes and Olefins
Enzymic Aldol Reactions of Aliphatic Nucleophiles and Hydroxy Aldehydes
Sesquiterpene Cyclizations Inside a Resorcinarene Capsule
Photocatalytic Asymmetric Radical Coupling of Ketones with N-Arylglycines
Selenonium Cations as Lewis Acid Organocatalysts
Enantioconvergent Intramolecular Nicholas Reaction towards Cyclic Ethers
Catalytic Enantioselective Formal [4+2] Cycloaddition to Functionalized Decalins
Strained Olefins Catalyze Halolactonizations
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Ausgabe 10/2018

Dynamic Kinetic Resolution of Azlactones with a Chiral DMAP Catalyst
Acid-Catalyzed Rearrangement of Hydroxylated Pinene Derivatives
Activating Ketones with Low Catalyst Loadings of a Potent Chiral Lewis Acid
Phosphoric Acid Catalyzed Aldehyde Addition to o-Quinone Methides
Enantioconvergent Biocatalytic Redoxisomerization of Pyranones
Triazolium-Salt-Catalyzed Dialkylation of Bisoxindoles
Enzymatic Control of the Stereochemical Course of [4+2] Cycloaddition
Chiral-Aldehyde-Catalyzed α-Functionalization of Glycine Esters
Fluorobissulfonylmethyl Iodides as Lewis Acid Catalysts
Biocatalytic Production of Linear α-Olefins from Carboxylic Acids
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Ausgabe 09/2018

Carbonyl-Catalyzed Biomimetic Asymmetric Mannich Reaction
Cooperative Lewis Base–Lewis Acid Catalysis for Iodochlorination of Alkenes
Asymmetric Photo-Organocatalytic C–H Functionalization of Toluene Derivatives
Proline-Catalyzed Asymmetric Inverse Electron Demand Diels–Alder Reaction
Chemo-Enzymatic Total Synthesis of Sorbicillinoids
α-Chiral Azahetaryl Ethylamines through Asymmetric Protonation
Unnatural Reactivity Enabled by Photoredox Catalysis in Oxidoreductases
An Alternative Mechanism for ‘Iminium-Ion’ Catalysis
Enantioselective Synthesis of Cyclopentenes via β-Azolium Ylides
Design of a Bifunctional Photoaminocatalyst for the Alkylation of Aldehydes
All PDFs of this category

Ausgabe 08/2018

Hydrogen-Bonding Phase-Transfer Catalyst Enabled Asymmetric Fluorination
9-Fluorenone as Photocatalyst for the Oxidation of Alcohols with Air
Enantioconvergent Allylation of (Arylpropargyl)acetates by an SN1 Reaction
Chiral Amidophosphate-Induced Halooxy- and Haloazacyclizations
Indanol as Scaffold for Chiral Organoiodine Catalysts
α-Oxidation of Cyclic Ketones with 1,4-Benzoquinone through Enol Catalysis
Organocatalytic Synthesis of Axially Chiral Sulfone-Containing Styrenes
Chiral Acid Catalyzed Asymmetric Cloke–Wilson Rearrangement
Whole-Cell Biotransformation of Benzene to Phenol
(–)-Ambrox Production by Biocatalysis Using Squalene Hopene Cyclase
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Ausgabe 07/2018

Bis(guanidino)iminophosphorane-Catalyzed Mannich-Type Reaction
Helically Chiral Anions for Inverse-Electron-Demand Diels–Alder Reactions
Cooperative Catalysis: Radical Addition to Olefins and Asymmetric Protonation
Stereodivergent Cyclopropanation of Nonactivated Alkenes
Enzymatic Synthesis of Highly Strained Carbocycles
Chiral Phosphoric Acid Catalyst for Desymmetrization of meso-Diones
Asymmetric Brønsted Acid Catalysts for Activation of Olefins
Ammonium Salt Catalyzed Monohalogenation of Phenols
Lewis Base Catalyzed Asymmetric Polyene Sulfenocyclization
Chiral-Acid-Catalyzed Asymmetric Dehydrative 4π Electrocyclization
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Ausgabe 06/2018

Cation Radical Diels–Alder Reactions via Asymmetric Counteranion-Directed Catalysis
Access to Enantioenriched Organosilanes from Enals and β-Silyl Enones
Acridinium-Mediated Photocatalytic Aliphatic C–H Functionalization
Mild Friedel–Crafts Alkylation Inside a Hexameric Resorcinarene Capsule
Hypervalent Iodine Derivatives as Halogen Bonding Based Organocatalysts
Ammonia Lyase Catalyzed Synthesis of Electron-Rich l-Phenylalanines
Chiral Aryl Iodide Catalyzed Fluoroamination of Cinnamyl Derivatives
Selenide-Catalyzed Asymmetric Construction of C–SCF3 Bonds
Superbase-Catalyzed Anti-Markovnikov Addition Reactions
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Ausgabe 05/2018

Enantioselective Cyclization by a Hexacoordinated Chiral Hydrogen Phosphate
Temperature-Directed Biocatalysis for the Production of Aromatic Aldehydes
Conjugate Reductions of Carbonyl Compounds with Diazaphospholenes
Enzymatic Kinetic Resolution of Secondary Thiols
Kinetic Resolution of Alcohols by Using a Recyclable Isothiourea Catalyst
Linked Dianionic Phase-Transfer Catalyst for Asymmetric Fluorocyclization
Stereoselective Enzymatic Synthesis of Heteroatom-Substituted Cyclopropanes
Intermolecular [4+2] Cycloadditions Catalyzed by an Artificial Enzyme Like Capsule
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Ausgabe 04/2018

Chemoenzymatic Distal C–H Hydroxylation
Supramolecular Brønsted Acid Catalyzed Carbonyl–Olefin Metathesis
Phosphine Oxide-Catalyzed γ-Umpolung Addition–Wittig Olefination
Sulfide-Catalyzed Cross-Coupling of Benzyl Halides and Boronic Acids
Purine Nucleoside Synthesis by Three-Component Dynamic Kinetic Resolution
β-Alkylation of Enals by Excited-State Iminium Catalysis
Site-Selective Oxidation of Macrolactones with a Single Biocatalyst
Construction of Halogenated Quaternary Carbon Centers
Bisguanidinium-Controlled Asymmetric Rearrangements of Acylsilanes
Desymmetrizing Asymmetric Selenoetherification
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Ausgabe 03/2018

Whole-Cell-Catalyzed Carbenoid B–H Insertion
Diazaphosphenium Triflate Catalyzed Hydroboration of Pyridines
Defluoroalkylation of Electron-Deficient Trifluoromethylarenes with Alkenes
Dynamic Kinetic Resolution of Aliphatic Aldehydes by Biocatalytic Amination
Asymmetric Aminalization by Cation-Binding Catalysis
Chiral Brønsted Acid Catalyzed Enantioselective Tandem Cyclization
Unnatural Amino Acid Ester Catalyzed Formal Synthesis of (+)-Pancracine
Synthesis of Chiral Acyclic Pyrimidine Nucleosides
Asymmetric Synthesis of 1,5-Diesters by Mukaiyama–Michael Reaction
Photocatalytic Aerobic Phosphatation of Simple Olefins
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Ausgabe 02/2018

Organocatalytic C(sp3)–H Amination through Nitrenoid Transfer
Asymmetric Silylium Catalysis Enabled by Hydrogen-Bond Donors
Iminium Catalysis inside a Self-Assembled Supramolecular Capsule
Visible-Light-Mediated Metal-Free Hydrosilylation of Alkenes
Cinchona Squaramide Catalyzed Asymmetric Domino Reaction
Biocatalytic Highly Enantioselective Oxidative Dearomatization of Phenols
BINOL-Catalyzed Reductive Petasis Borono-Mannich Reaction of Enals
Anthraquinones as Photoredox Organocatalysts
A Catalytic Enantioselective Prototopic Shift/Furan Diels–Alder Cascade
Atroposelective Synthesis of Axially Chiral Biaryl Amino Alcohols
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Ausgabe 01/2018

Enzymatic Anti-Markovnikov Oxidations of Styrenes
Kinetic Resolution of anti-1,3-Diols by Horeau Amplification
Organic Photoredox-Catalytic Arene C–H Amination with Primary Amines
Photoredox-Catalytic Nucleophilic Aromatic Substitution of Alkoxyarenes
Corrigendum: Cyclobutadienes via an Organocascade
Organocatalytic Asymmetric Reduction of N-Alkyl Aryl Imino Esters
Phosphine-Catalyzed [4+4] Annulation to Construct Eight-Membered Rings
Tetraarylphosphonium Salt-Catalyzed Synthesis of Oxazolidinones
Enzymatic Olefin Cyclopropanation under Aerobic Conditions
Lactate-Based Ionic Liquid Catalyzed Reductive Amination–Cyclization
Oxidative Asymmetric [2+3] Annulation of Aldehydes with Azomethine Imines
Catalytic Asymmetric Synthesis of Isoindolinones
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Ausgabe 12/2017

Photoredox-Catalyzed Hydrocarboxylation of Styrenes in Continuous Flow
Imidodiphosphorimidate-Catalyzed Asymmetric Cycloaddition of Dienes with Aldehydes
Photoredox-Initiated Radical Addition of Alkenes to Carbonyls
Amidation of Carboxylic Acids by Using Carboxylic Acid Reductases
Asymmetric Enzymic Reduction of Structurally Diverse Ketones
Biocatalytic Regioselective para-Carboxylation of Catechols
Organo-Photoredox Catalysis of a Retro-Smiles Rearrangement
Enantioselective Photoreduction of Activated Ketones and Ketimines
Asymmetric Betti/Aza-Michael Sequence
Iterative Catalyst Design for Amino Acid–Thioester Condensation
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Ausgabe 11/2017

Cyclobutadienes via an Organocascade
Flavin-Dependent Ene-Reductase-Catalyzed Hydrogen Atom Transfer
Simple Nucleophiles for α,β-Unsaturated Acyl Ammonium Catalysis
Chiral Biphenyl-Based Thiourea/Amine Catalyst for the Henry Reaction
Enantioselective cis-Aziridination of α,β-Unsaturated Aldehydes
Methanobenzo[7]annulene Synthesis by Asymmetric [3+2] Cycloaddition
Oxidative Photoredox-Catalyzed Imino-Functionalizations of Olefins
Enantioselective Synthesis of Nitriles by Enzymatic Dehydration of Oximes
Elucidating the Biosynthetic Mechanism toward the Quinaldic Acid Moiety
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Ausgabe 10/2017

Highly Enantioselective Organocatalysis with a Mechanically Interlocked Molecule
A Light-Driven Organocatalytic Aldol Desymmetrization Strategy
Organocatalytic Enantioselective Intramolecular Povarov Reaction of Anilines
Enzyme-Catalyzed Direct Alkylation of Amines with Alcohols
Regioselective Organocatalytic Hydroformylation of Aryl Alkenes
Biocatalytic Access to Challenging Tryptophan Analogues
Amine-Catalyzed Mannich Reactions with Activated Ketimines
Asymmetric Cycloadditions of Nitrile Oxides to o-Hydroxystyrenes
Oxidative [4+3] Cycloaddition of Allenamides and Furans
Biocatalyzed Formal Anti-Markovnikov Alkene Hydroamination and Hydration
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Ausgabe 09/2017

Enzyme-Catalyzed Enantioselective Reductive Amination
Enantioselective Aza-pinacol Rearrangement of Indoles
Directed Evolution toward an Iron-Heme Enzyme for Asymmetric C–H Amination
Enzymatic Friedel–Crafts Acylation and Fries Rearrangement
Enantioselective Photocatalytic α-Alkylation of Aldehydes
Asymmetric α-Fluorination of α-Branched Enals
Catalyst-Controlled Diastereoselectivity Switch in Conjugate Additions
Enantioselective Diels–Alder Cycloaddition to Construct Carbazolespirooxindoles
Organo- and Biocatalytic Sequential Transformation of Alcohols into Amines
Enantioselective Conjugate Additions of Indoles Catalyzed by Fiaud’s Acid
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Ausgabe 08/2017

NHC-Catalyzed Oxidative [4+2] Annulation of 2-Hydroxybenzaldehydes and Ketones
Chiral Fullerene-Derived Thioureas as Recyclable Asymmetric Organocatalysts
Catalytic Stereoselective Synthesis of Pronucleotides
A Shuttling Strategy for the Enantioselective β-Protonation of Enals
Enantioselective Photoorganocatalytic Formal α-Alkylation of Aldehydes
Total Synthesis of (+)-Rishirilide B through Oxidative Kinetic Resolution
Chemoenzymatic Route to Chiral Gamma Secretase Inhibitor Intermediates
Chiral Phosphoric Acid Catalyzed Kinetic Resolution of 2-Pyridyl Esters
Construction of a Quaternary Carbon by a Mannich Reaction
Direct Hydroxylation of Benzene to Phenol by Cytochrome P450BM3
N-Heterocyclic Carbene Catalyzed Oxidative Spirocyclization of Indoles
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Ausgabe 07/2017

Acyloin Rearrangement of α-Hydroxy Acetals to α-Alkoxy Ketones
Biocatalyzed Intramolecular Benzoin Reaction
NHC-Catalyzed [4+2] Annulation of Enals with Electron-Deficient 2,4-Dienes
A Three-Component Enantioselective aza-Darzens Reaction
Enantioselective Synthesis of Vicinal Diamines
Catalytic Asymmetric Electrochemical Coupling of Amines with Ketones
N-Heterocyclic Carbene Catalyzed Disulfide Metathesis and Phosphorylation
Ketoreductase-Catalyzed Stereoselective Synthesis of 4-Aminocyclohexanols
Organocatalytic Enantioselective Synthesis of Dihydrophenanthridines
Asymmetric Enzymatic Cyclopropanation with Ex Situ Generated F3CCHN2
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Ausgabe 06/2017

Silylium Ion Catalyzed C–H Arylation of Hydrocarbons
Brønsted Acid Catalyzed Hydro-functionalization of Unactivated Alkynes
Brønsted Acid Catalyzed [2+2] Photocycloaddition Reactions
Regioselective Organocatalytic Olefin Hydroamination with 1,2,3-Triazoles
Catalytic Enantioselective N-Alkylation of Indoles by Aza-para-quinone Methides
Asymmetric Catalysis via Cyclic Aliphatic Oxocarbenium Ions
N-Heterocyclic Carbene Catalyzed Truce–Smiles Rearrangement
C–H Pyridination with Organoselenium Catalysts
A Systematic Investigation of Intramolecular Sulfenofunctionalizations of Alkenes
Visible-Light-Promoted [2+2+2] Cyclization of Alkynes with Nitriles
Organocatalytic Redox Deracemization of Cyclic Benzylic Ethers
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Ausgabe 05/2017

Intramolecular [4+2] Cycloaddition of ortho-Quinone Methides Generated In Situ
Bioelectrochemical Nitrogen Reduction
Biocatalytic Synthesis of β-Hydroxydioxinones
N-Heterocyclic Carbene Catalyzed Synthesis of 3,4-Dihydrocoumarins
Asymmetric Alkylation of Anthrones for the Total Synthesis of Viridicatumtoxin B
Reusable Polymer-Based Catalysts for the Asymmetric Steglich Rearrangement
Biocatalytic Enantioselective Hydroalkoxylation
Catalytic γ-Addition of 2-Allylazaarenes to Isatins and Trifluoromethyl Ketones
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Ausgabe 04/2017

Kinetic Resolution of Primary Amines through Chiral Phosphoric Acid Catalysis
Stereospecific Glycosylation through Catalytic Stereoinversion
Photoredox Activation of Carbon Dioxide in an α-Amino Acid Synthesis
A Novel Baeyer–Villiger Monooxygenase for Bulky Substrates
Enantioselective Synthesis of Chiral Oxime Ethers
A Diazaphospholene Precatalyst for Imine and Conjugate Reductions
Catalytic Regio- and Enantioselective [6+2], [4+2], and [2+2] Cycloadditions
Catalytic Asymmetric Synthesis of Atropisomeric Biaryls
Enamine and Iminium Catalysis with an Evolved Carboligase
Synthesis of Furan Atropisomers by Central-to-Axial Chirality Conversion
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Ausgabe 03/2017

Nonnatural Reactivity of Cofactor-Dependent Enzymes upon Light Irradiation
Catalytic Asymmetric Umpolung Reactions of Imines with Enones
Asymmetric Catalytic Polyene Bromocyclization
Optically Switchable Helicenes for an Enantiodivergent Steglich Rearrangement
Cation Binding Catalysis for Enantioenriched Dioxazinanes and Dioxazepanes
Large-Scale Biocatalytic Oxidation of a Sulfone to a Chiral Sulfoxide
Organocatalytic Stereoselective [8+2] and [6+4] Cycloaddtions
1,1,3,3-Tetratriflylpropene: A Strong Brønsted or Lewis Acid Catalyst
Asymmetric Synthesis of Rauhut–Currier-type Products by Bifunctional Catalysis
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Ausgabe 02/2017

Asymmetric Enzymatic Carbon–Silicon Bond Formation
Phosphoric Acid Catalyzed Asymmetric Synthesis of SPINOL Derivatives
Catalytic Enantioselective Vinylogous Pinacol Rearrangement
Construction of Adjacent Quaternary Stereocenters
Annulation of Donor–Acceptor Cyclobutanes with N-Heterocyclic Carbenes
Photocatalytic Hydrodefluorination Promoted by π-Hole–π Interactions
Hydrogen-Bonding Catalysis with Sulfonium Salts
Catalytic Asymmetric Synthesis of C2-Symmetric Secondary Amines
Transaminase-Catalyzed Enantioselective Synthesis of Piperidines
ortho-Selective Chlorination of Anilines
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Ausgabe 01/2017

Allylboration of Aldehydes by Immobilized TRIP
Asymmetric Oxidative Dearomatization/Oxa–Michael Addition Sequence
Catalytic Asymmetric Aminoalkynylation of Arenes
Regiodivergent Chlorination of Phenols Controlled by a Lewis Base Catalyst
Regioisomeric Fluorolactonization via Hypervalent Iodine Catalysis
Electrostatically Enhanced Phosphoric Acids in Brønsted Acid Catalysis
Enantioselective Aza–Sakurai Cyclization
Organocatalytic Asymmetric Vinylogous Prins Cyclization
Enantioselective Catalytic Thioacetalization of Aldehydes
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Ausgabe 12/2016

Highly Enantioselective Addition of Allyltrimethylsilane to Aldehydes
Asymmetric Synthesis of Spirobiindanones by Catalytic C-Acylation
Base-Catalyzed Stereospecific Isomerization of Allylic Alcohols and Ethers
Kinetic Resolution of Axially Chiral Quinolines by Transfer Hydrogenation
Asymmetric Synthesis of Chromans Bearing Oxindole Scaffolds
Thiourea-Catalyzed Michael Addition of Alkanethiols to β-Substituted Acrylates
Asymmetric Phosphine Catalysis Toward Benzylic Ethers
N-Heterocyclic Carbene Catalyzed β-Amination of Enals
Chiral N,N′-Dioxide-Organocatalyzed Michael Addition–Alkylation Reaction
Dimeric BINOL-Derived Disulfonimide Mukaiyama–Mannich Catalyst
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Ausgabe 11/2016

Novel Pyridoxamines for Enantioselective Biomimetic Transamination
Asymmetric Synthesis by Pathway Engineering of an Enzymatic Cascade
Kilogram-Scale Enzymatic Resolution of 1-Methyl 4-tert-Butyl 2-Propylsuccinate
Carboxylic Acid Modified BINOL Phosphate Catalysis
Phosphine-Catalyzed Domino Annulations of Allenoates and Ketimines
Catalytic Enantioselective Dearomatization of Pyridines with C-4 Selectivity
Catalytic Site- and Enantioselective Aldolizations of Diketones and Aldehydes
NHC-Catalyzed Enantioselective Tropane Synthesis
The Cope Rearrangement via Iminium Catalysis
Catalytic Asymmetric Prins Cyclization
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Ausgabe 10/2016

Catalytic Asymmetric Geminal Difluorination of β-Substituted Styrenes
Asymmetric Mannich Reaction of Aliphatic N-Boc Imines
Biocatalytic Asymmetric Synthesis of Bulky Amines
Indolinecarboxylate-Catalyzed Enantio-selective oxa-Pictet–Spengler Reaction
Chiral Pyridoxamine Catalyzed Transamination of α-Keto Acids
Ser-His is Not a Microprotease
Catalytic Cyanotritylation of Aldehydes
Imidophosphate-Catalyzed Enantioselective Oxa-Pictet−Spengler Reaction
Hydrogen-Bonding Catalysis with Tetraalkylammonium Salts
Vanadium Chloroperoxidase Catalyzed Aza-Achmatowicz Reaction
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Ausgabe 09/2016

Single-Step Enzymatic Synthesis of β-Methyltryptophans
Brønsted Acid Catalyzed Synthesis of Chiral Tetrahydroacridines
Brønsted Acid Catalyzed Transfer Hydrogenation of Imines and Alkenes
Chiral NHC-Catalyzed Benzoin Reaction Permits a Dynamic Kinetic Resolution
Enantioselective Intermolecular [2+2] Photocycloaddition
Conformational Control of Thiourea Catalysts for Improved Performance
Enantioenriched γ-Butenolides via Chiral Electrophilic Selenium Catalysis
Alkynylogous Mukaiyama Aldol Reaction
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Ausgabe 08/2016

N-Hydroxyphthalimide-Catalyzed Electrochemical Allylic Oxidation
A New Substituent for BINOL-Phosphate Catalysis
Proline-Catalyzed Enantioselective Synthesis of 2,3-Disubstituted Piperidines
Triflic Acid Catalyzed Enyne Cyclization
Iminium Catalysis in a Supramolecular Host
An Organocatalytic Approach to Enantiopure 2H- and 3H-Pyrroles
Organocatalytic Construction of Spiroindane Derivatives
Visible-Light-Promoted Synthesis of Benzo[b]phosphole Oxides
One-Pot Biocatalytic Cascade to Substituted Piperidines and Pyrrolidines
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Ausgabe 07/2016

Enantioselective Formation of Quaternary Carbons by Radical Conjugated Addition
Catalytic Diastereoselective Difluorination of Alkenes
Biocatalytic syn-Selective Aldol Reaction of Fluoropyruvate
Desymmetrization of Cyclohexanones by Enantioselective α-Arylation
Trifunctional Squaramide Catalyzed Enantioselective Henry Reaction
Development of a Binaphthyl-Based Chiral DMAP Catalyst
Photobiocatalytic Reduction of α,β-Unsaturated Enones and Amides
Organocatalytic Transformation of Epoxides into Thiiranes
Asymmetric Catalysis with CO2: The Direct α-Allylation of Ketones
Lewis Acid Catalyzed Formal [3+2] Cycloaddition of Cyclopropyl Acetals
Enantioselective Organocatalytic [4+2] Cycloaddition on Water
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Ausgabe 06/2016

Direct Mannich-Type Reaction Using a Chiral Organosuperbase Catalyst
Organocatalytic Kinetic Resolution of Sulfoximines with Enals
Enzymatic Nitrene Transfer/Sigmatropic Rearrangement to Access Allylic Amines
Asymmetric Ugi Reaction Catalyzed by a Chiral Phosphoric Acid
Data Set Design for the Asymmetric Fluorination of Allylic Alcohols
Biomimetic Photoorganocatalytic Chlorination of Arenes
Enantioselective Synthesis of Silacyclopentanes
NHC-Catalyzed Enantioselective Enamide−Aldehyde Cross-Coupling
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Ausgabe 05/2016

A Silylated C–H Acid Catalyst for Asymmetric Diels–Alder Reactions of Cinnamates
Diol-Catalyzed Enantioselective Diboration of Alkenes
Hypervalent Iodine-Catalyzed Dimerization of Styrenes
Organocatalytic Asymmetric Mannich Reaction through Hydrogen Bonding
Efficient Total Biosynthesis of Opiates by Using Engineered Escherichia Coli
One-Pot Cascade of Synergistic Catalysis toward Tetrahydroisochromenes
Hypervalent Iodine Catalyzed Oxidative Phenol Couplings
Oxyallyl Cation Catalysis
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Ausgabe 04/2016

Phosphoric Acid Catalyzed [4+2] Cycloadditions and Imino–Ene Reactions
Chiral Phosphoric Acid Catalyzed Self-Redox Reaction of Indolines
Enantioselective Aldol Reactions with Fluoroacetate Surrogates
Biocatalytic Olefination of Aldehydes
Enol Catalysis with α-Branched Ketones and a Michael Acceptor Surrogate
Redox Esterification of α- and β-Substituted α,β-Unsaturated Aldehydes
Diels–Alder Trapping of Photochemically Generated Hydroxy-o-Quinodimethanes
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Ausgabe 03/2016

Strong Hydrogen-Bonding Organocatalysts Activated by Electrostatics
Organocatalytic Enantioselective Desymmetrization of Oxetanes
Whole-Cell Biocatalysts for Stereoselective C–H Amination Reactions
C1-Symmetric Chiral Brønsted Acid Catalyzed Diels−Alder Reaction
Regiodivergent Enantioselective Addition of Oxazolones
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Ausgabe 02/2016

Biocatalytic One-Pot Synthesis of l-Tyrosine Derivatives
Asymmetric α-Coupling of N-Arylaminomethanes with Aldimines
Organocatalytic Asymmetric 2-Aza-Cope Rearrangement
Enantioselective Construction of Tertiary Stereocenters
Hypervalent Iodine Catalyzed Asymmetric Vicinal Dioxygenation of Alkenes
Addition of 2-Alkoxycarbonyl-1,3-dithianes to Imines
Aza-Michael Addition with a Chiral Phosphoric Acid Catalyst
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Ausgabe 01/2016

Highly Diastereoselective Triflimide-Catalyzed Mukaiyama Aldol Reaction
Organocatalytic Asymmetric Passerini Reaction
Asymmetric Dearomatizing Michael Addition of β-Naphthols
Organocatalytic Diels–Alder Reaction to Access Norcamphor Scaffolds
Aminothiourea-Catalyzed Asymmetric Synthesis of Spiroketals
Enantioselective Biocatalytic Dealkylation of N-Benzylisoquinolines
Enantioselective Organocatalytic Trichloromethylation with Chloroform
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Ausgabe 12/2015

Organocatalytic Photoredox C–H Amination of Arenes
1,6-Conjugate Addition of Pyrroles to para-Quinone Methides
Biocatalytic Hydrogen-Borrowing Amination of Ketones
Organocatalytic Carbonyl–Ene Cyclization
C–H Alkylation of Alcohols
The Mitsunobu Reaction Catalytic in Phosphine and Azodicarboxylate
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Ausgabe 11/2015

Enzymatic cis-Dihydroxylation of Alkenes
Rigid Cationic Multidentate Halogen Bond Donor Catalysts
Switchable Organocatalytic Annulation Reactions
1,4-Iodofunctionalizations of Conjugated Dienes
Catalytic Heteroarene C-Alkylation with Alcohol-Derived Radicals
Phosphoric Acid-Catalyzed Asymmetric Nitroso-Diels–Alder Reaction