Synthesis of Alkoxynitrostilbenes as Chromophores for Nonlinear Optical Materials

Vincent Diemer; Hélène Chaumeil; Albert Defoin; Christiane Carré

doi:10.1055/s-2007-990808

PAPER

Synthesis of Alkoxynitrostilbenes as Chromophores for Nonlinear Optical Materials

Vincent Diemer^a, Hélène Chaumeil*^a, Albert Defoin^a, Christiane Carré^b
^a Laboratoire de Chimie Organique et Bioorganique, CNRS UMR 7015, Ecole Nationale Supérieure de Chimie de Mulhouse, Université de Haute Alsace, 3 rue Alfred Werner, 68093 Mulhouse Cedex, France
Fax: +33(3)89336875; e-Mail: helene.chaumeil@uha.fr;
^b FOTON, CNRS UMR 6082, GET-ENST Bretagne, Département Optique, Technopôle Brest Iroise, CS 83818, 29238 Brest Cedex, France

Abstract

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Abstract

The synthesis of different unsymmetrical new alkoxynitrostilbenes bearing one or two monomers groups, as optimized nonlinear optical (NLO) chromophores, are described herein. The considered functions were acrylate and triethoxysilyl groups. The goal is to synthesize molecules with a large quadratic NLO polarizability and relative high solubility in photopolymerizable media that could also be permanently frozen by orientation in an electric field and photopolymerization.

Key words

chromophores - stilbene - monomers - crossed monomers - nonlinear optics

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References

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