New Acylated Cyanogenic Diglycosides from Fruits of Anthemis cairica

Adolf Nahrstedt; Victor Wray; Lutz Grotjahn; Lucie H. Fikenscher; Robert Hegnauer

doi:10.1055/s-2007-969835

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Planta Med 1983; 49(11): 143-148
DOI: 10.1055/s-2007-969835

Research Articles

New Acylated Cyanogenic Diglycosides from Fruits of Anthemis cairica

Adolf Nahrstedt¹ , Victor Wray² , Lutz Grotjahn² , Lucie H. Fikenscher³ , Robert Hegnauer³

¹Institut für Pharmazeutische Biologie der Technischen Universität, Braunschweig, West-Germany
²Gesellschaft für Biotechnologische Forschung, Braunschweig-Stöckheim, West-Germany
³Laboratorium voor Experimentele Plantensystematiek, Rijksuniversiteit Leiden, NL-Leiden, The Netherlands

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Publication History

1983

1983

Publication Date:
26 March 2007 (online)

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Abstract

Three new cyanogenic diglycosides of the mandelonitrile series have been isolated from fruits of Anthemis cairica (Compositae) and their structures identified by degradation and spectral methods mainly ¹H-NMR, ¹³C-NMR, FAB-MS. Minor compounds are 2-β-primeverosyloxy-2-phenyl-2S-acetonitrile (epilucumin) and its 4″-p(β-D-glucopyranosyloxyl-(E)cinnamate; the main compound is the 4″-p(β-primeverosyloxy)-(E)cinnamate of epilucumin.

Key Word Index

Anthemis spp. - Compositae - Cyanogenic glycosides - Mandelonitrile glycosides - p-Glycosyloxy-cinnamic acid esters - ¹H-NMR, ¹³C-NMR, FAB-MS.