Phosphomolybdic Acid: Mild and Efficient Catalyst for Acetylation of Alcohols, Phenols, and Amines under Solvent-Free Conditions

Santosh T. Kadam; Sung Soo Kim

doi:10.1055/s-2007-1000859

PAPER

Phosphomolybdic Acid: Mild and Efficient Catalyst for Acetylation of Alcohols, Phenols, and Amines under Solvent-Free Conditions

Santosh T. Kadam, Sung Soo Kim*
Department of Chemistry, Inha University, Incheon 402-751, Korea
Fax: +82(32)8675604; e-Mail: sungsoo@inha.ac.kr;

Abstract

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Abstract

Phosphomolybdic acid (PMA) has been found to be a simple and efficient catalyst for the acetylation of alcohols, phenols, and amines. Acetylation reactions with acetic anhydride (1.0 equiv) proceed in excellent yield in the presence of a catalytic amount (0.2 mol%) of PMA at ambient temperature within a relatively short reaction time (<10 min). Structurally diverse alcohols, phenols, and amines undergo acetylation under solvent-free conditions.

Key words

acetylation - phosphomolybdic acid - alcohols - amines - green catalysis

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References

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