Catalytic, Enantioselective Hetero-Diels-Alder Reaction with Novel, Chiral Bis-Titanium(IV) Catalyst

Abstract

Our recently designed chiral bis-titanium(IV) catalyst can be successfully utilized for the catalytic enantioselective hetero-Diels-Alder reaction of aldehyde and Danishefsky’s diene. The high asymmetric induction is achievable in the case of sterically less hindered aldehydes.

hetero-Diels-Alder - asymmetric synthesis - catalyst - titanium(IV) complex

References

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