Download PDF
Synlett 2001; 2001(8): 1260-1262
DOI: 10.1055/s-2001-16050
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

A Convenient Access to Perfluoroalkyl Selenoethers and Selenyl Chlorides

Emmanuel Magnier* , Erica Vit, Claude Wakselman
  • *SIRCOB-CNRS, Bâtiment Lavoisier, Université de Versailles-Saint Quentin, 45 avenue des Etats-Unis, 78035 Versailles, France; Fax 33 1 39 25 44 52; E-mail: wakselma@chimie.uvsq.fr
Further Information

Publication History

Publication Date:
31 December 2001 (online)

  PDF Download  Permissions and Reprints All articles of this category

The treatment of diselenides with different perfluoroalkyl iodides in the presence of sodium hydroxymethanesulfinate led to perfluoroalkyl selenides in fair to good yields. The reaction between benzyl perfluorooctyl selenide and chlorine, or sulfuryl chloride, gave rise to the corresponding selenyl chloride and represents an easy route to perfluoroalkylselenyl chlorides.

fluorinated alkyl halides - selenium derivatives - electron transfer - selenyl chloride - cleavage by chlorine

      >