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Synthesis 2001; 2001(4): 0626-0632
DOI: 10.1055/s-2001-12351
DOI: 10.1055/s-2001-12351
paper
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Bridged 1-Methylbisimidazoles as Building Blocks for Mixed Donor Bi- and Tridentate Chelating Ligands
Further Information
Publication History
Publication Date:
31 December 2001 (online)
Novel bi- and tridentate imidazole chelate ligands consisting of varying donor sets were prepared using an efficient one- or two-step procedure. Keto- and methylene-bridged bisimidazoles 1, 2 served as versatile starting materials for the introduction of additional donor groups, thus allowing the facile variation of donor sets within a bisimidazole ligand framework.
heterocycles - imidazoles - ligands - phosphines