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Synthesis 2001; 2001(3): 0473-0477
DOI: 10.1055/s-2001-11442
DOI: 10.1055/s-2001-11442
paper
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Conversion of Fused-ring Isoxazolidines to α-(Hydroxymethyl)lactones by 3-Chloroperbenzoic Acid
Further Information
Publication History
Publication Date:
31 December 2001 (online)
MCPBA treatment of fused-ring isoxazolidines furnishes α-(hydroxymethyl)substituted cyclic ketones, which constitute the starting-point for a successive Baeyer-Villiger oxidation allowing the synthesis of novel α-(hydroxymethyl)lactones.
β-hydroxyketones - α-(hydroxymethyl)lactones - Baeyer-Villiger oxidation - isoxazolidines - 3-chloroperbenzoic acid