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Synthesis 2000; 2000(3): 403-406
DOI: 10.1055/s-2000-6347
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Catalytic Aerobic Oxidative Cleavage of Oximes, Tosylhydrazones and N,N-Dimethylhydrazones to Carbonyl Compounds

Gonzalo Blay* , Elisabeth Benach, Isabel Fernández, Sales Galletero, José R. Pedro, Rafael Ruiz
  • *Departament de Química Orgànica, Facultat de Química, Universitat de València, E-46100-Burjassot (València), Spain; Fax + 34(9 63)86 43 28; E-mail: Jose.R.Pedro@uv.es
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Publication Date:
31 December 2000 (online)

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A new method for the aerobic oxidative cleavage of the C=N double bond of oximes and, tosyl- and N,N-dimethylhydrazones of ketones to yield their corresponding carbonyl compounds, with a Ni(II) complex catalyst, oxygen and pivalaldehyde has been developed.

protective groups - ketoxime - hydrazone - metal catalyst - Ni(II) complex

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