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Synthesis 1997; 1997(11): 1331-1337
DOI: 10.1055/s-1997-1338
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One-Pot Synthesis of Secondary and Tertiary Amines by Carbonylative Hydroaminomethylation of Alkenes Catalyzed by Di(μ-chloro)bis(η 4-1,5-cyclooctadiene)dirhodium

Thorsten Rische, Peter Eilbracht*
  • *Organische Chemie I (FB 3), Universität Dortmund, Otto-Hahn-Str. 6, D-44221 Dortmund, Germany, Fax +49(231)7555363; E-mail: eilbrach@citrin.chemie.uni-dortmund.de
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Publication Date:
31 December 2000 (online)

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Secondary and tertiary amines are selectively prepared with high yields by the reaction of alkenes with primary or secondary amines, carbon monoxide and hydrogen in the presence of [Rh(cod)Cl]2 as catalyst via a one-pot hydroformylation - amine condensation - reduction sequence.

hydroaminomethylation - hydroformylation - amines - transition metal rhodium catalysis - amidones