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Synlett 1996; 1996(10): 990-992
DOI: 10.1055/s-1996-5645
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Some Intermolecular Pauson-Khand Reactions of Functionalised Alkylidenecyclopropanes

Hervé Corlay, Ian W. James, Eric Fouquet, Jörn Schmidt, William B. Motherwell*
  • *Departments of Chemistry, Christopher Ingold Laboratories, University College London, 20 Gordon Street, London WC1H 0AJ, UK
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Publication History

Publication Date:
31 December 2000 (online)

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Functionalised alkylidenecyclopropanes undergo efficient intermolecular Pauson-Khand reactions to give bi- and tricyclic skeletons with preservation of a spirocyclic cyclopropyl unit. The observed regio- and stereoselectivities are, in part, determined by the nature of these substituents.

Functionalised Alkylidenecyclopropanes - Intermolecular Pauson-Khand reaction

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