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Synlett 1996; 1996(5): 475-476
DOI: 10.1055/s-1996-5443
DOI: 10.1055/s-1996-5443
letter
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To Tandem or Not to Tandem: Metal-Induced Rearrangements of Distannyl- and Silylstannyl-substituted Diallyl and Allyl Vinyl Ethers
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Publication History
Publication Date:
31 December 2000 (online)
Triisobutylaluminium is effective in inducing the Claisen rearrangement of distannyl- and silylstannyl-substituted allyl vinyl ethers. While the ruthenium-catalysed tandem rearrangement of the corresponding diallyl ethers is possible, it is accompanied by side reactions and appears to be limited in scope to the silylstannyl-substituted compounds.
allyl ethers - vinyl ethers - Claisen - tandem rearrangement - organotin - organosilicon