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Synlett 1996; 1996(4): 341-342
DOI: 10.1055/s-1996-5411
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1,4-Reductive Addition of Hydrazoic Acid

Elias A. Couladouros* , Costas D. Apostolopoulos
  • *Chemical Laboratories, Agricultural University of Athens, Iera Odos 75, Athens 118.55, Greece
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Publication Date:
31 December 2000 (online)

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The reductive addition of hydrazoic acid to γ-keto-α,β-unsaturated dicarbonyl substrates is discussed. Application for the synthesis of unnatural aminoacids and peptides is also presented.

unnatural aminoacids - γ-keto aminoacids - α,β-unsaturated-γ-keto-δ-lactones - hydrazoic acid - 2H-pyran-3(6H)-ones

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