PDF herunterladen
Synthesis 1996; 1996(10): 1153-1176
DOI: 10.1055/s-1996-4369
review
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

On the Use of Stable Organic Nitroxyl Radicals for the Oxidation of Primary and Secondary Alcohols

Arjan E. J. de Nooy, Arie C. Besemer, Herman van Bekkum*
  • *Delft University of Technology, Laboratory of Organic Chemistry and Catalysis, Julianalaan 136, NL-2628 BL, Delft, The Netherlands, Fax +31(15)2781415
Weitere Informationen

Publikationsverlauf

Publikationsdatum:
31. Dezember 2000 (online)

  als PDF herunterladen  Lizenzen und Reprints Alle Artikel dieser Rubrik

This article reviews the oxidation of primary and secondary alcohols using nitroxyl radicals from the first publication in which this reaction was described in 1965. A variety of stoichiometric and catalytic methods is discussed, with reactions in organic solvents, under biphasic conditions as well as in water. Mechanistic studies and general experimental procedures are included. The high regioselectivity for the oxidation of primary alcohols that can be achieved in the presence of secondary alcohols is emphasised.

Catalytic and stoichiometric oxidation methods using nitroxyl radicals for a wide range of alcoholic substrates are reviewed.

      >