Download PDF
Synthesis 1996; 1996(4): 473-474
DOI: 10.1055/s-1996-4233
short paper
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

An Unusual N-Alkylation Reaction During the Oxidative Addition of Hexafluoroacetone and Tetrachloro-o-benzoquinone to P-Bis(2-chloroethyl)amino-Substituted λ 3P-Compounds

Ion Neda, Carsten Melnicky, Alexander Vollbrecht, Reinhard Schmutzler*
  • *Institut für Anorganische und Analytische Chemie der Technischen Universität, Postfach 3329, D-38023 Braunschweig, Germany, Fax +49(531)3915387
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

The reaction of 2,3-dihydro-1,3,2-benzodiazaphosphinin-4(1H)-ones 1a-d with hexafluoroacetone took an unusual course with formation of the tricyclic phosphoranes 5a-d. Similar products 6a, c, d were obtained by treatment of 1a, c, d with tetrachloro-o-benzoquinone.

oxidative addition - N-alkylation - benzodiaza-λ 3-phosphorinones - tricyclic phosphoranes

      >