Download PDF
Synlett 1995; 1995(5): 463-464
DOI: 10.1055/s-1995-4987
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Asymmetric Synthesis of (+)-Methyl Epijasmonate and (-)-Methyl Curcurbate

Heinz Stadtmüller, Paul Knochel*
  • *Fachbereich Chemie der Philipps-Universität Marburg, Hans Meerwein Sraße, D-35032 Marburg, Germany
Further Information

Publication History

Publication Date:
31 December 2000 (online)

  PDF Download  Permissions and Reprints All articles of this category

A short enantio- and diastereoselective synthesis of (+)-methyl epijasmonate 1 and (-)-methyl curcurbate 2, two essential components of jasmin oil is described. The key step is a nickel catalyzed ring closure, which sets up three chiral centers with high diastereoselectivity.

jasmonoids - catalytic enantioselective synthesis - nickel catalyzed carbozincation

      >