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Synthesis 1994; 1994(7): 714-718
DOI: 10.1055/s-1994-25555
DOI: 10.1055/s-1994-25555
paper
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Total Synthesis of 2-Tetraprenylbenzoquinol and -benzoquinone
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Publikationsverlauf
Publikationsdatum:
17. September 2002 (online)
The total synthesis of 2-tetraprenylbenzoquinol and -benzoquinone is described. A key step in this synthesis is the highly regio- and stereoselective coupling between an appropriate aromatic allylcarbonate and an activated bifunctional farnesyl derivative using Pd(PPh3)4 as catalyst.