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Synlett 1993; 1993(4): 277-278
DOI: 10.1055/s-1993-22430
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Organozinc Reagents in Synthesis; 1. The Facile Rearrangement of 1-Trimethylsilyl-2-propenylzinc Reagents: The Uncatalysed Reaction

J. J. Eshelby* , P. C. Crowley, P. J. Parsons
  • *Department of Chemistry, University of Reading, P.O. Box 224, Reading, Berkshire, RG6 2AD, England and Zeneca Agrochemicals, Jealotts Hill Research Station, Bracknell, Berkshire, RG12 6EY, England
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Publication Date:
19 March 2002 (online)

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Treatment of 2-[1-trimethylsilyl-2-propenyl]lithium with zinc chloride affords 1-[2-trimethylsilyl-2-propenyl]zinc chloride which can be trapped with a range of electrophiles.

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