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Synlett 1992; 1992(4): 301-302
DOI: 10.1055/s-1992-21347
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Facile Allylation of Ethyl 4,4,4-Trifluoroacetoacetate by Palladium Catalysis

Isao Shimizu* , Masashi Toyoda, Toru Terashima, Masato Oshima, Hajime Hasegawa
  • *Department of Applied Chemistry, School of Science and Engineering, Waseda University, Shinjuku-ku, Tokyo 169, Japan
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Publication Date:
08 March 2002 (online)

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Allylation of ethyl 4,4,4-trifluoroacetoacetate was carried out by reaction with allylic acetates, carbonates or alcohols in the presence of a palladium catalyst to give ethyl 2-allyl-4,4,4-trifluoroacetoacetates in good yield.

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