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Synlett 1992; 1992(2): 114-116
DOI: 10.1055/s-1992-21282
DOI: 10.1055/s-1992-21282
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved.
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or duplication of any kind, translating, preparation of microfilms, and electronic
data processing and storage.Synthetic Studies Toward Paenoiflorin: Preparation of the Highly Functionalized Pinane Skeleton Utilizing Intramolecular Hosomi-Sakurai Reaction
Further Information
Publication History
Publication Date:
08 March 2002 (online)

An efficient route to the highly functionalized pinane unit present in paeniflorin (1) is described. The sequence employs the newly developed reagent, [4-(1,3-dithian-2-yl)-2-butenyl]trimethylsilane (6), which serves as an annulating agent by a combination of Michael addition and intramolecular Hosomi-Sakurai reaction.