Download PDF
Synlett 1991; 1991(8): 555-556
DOI: 10.1055/s-1991-20794
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Synthesis of Allyloxiranes from Allyltributyltin and α-Halo Ketones Catalyzed by Dibutyltin Dihalide-Hexamethylphosphoric Triamide Complexes

Katsunori Yano* , Yukio Hatta, Akio Baba, Haruo Matsuda
  • *Department of Applied Chemistry, Faculty of Engineering, Osaka University, 2-1 Yamada-Oka, Suita, Osaka 565, Japan
Further Information

Publication History

Publication Date:
07 March 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

Dibutyltin dihalides act as versatile catalysis in combination with hexamethylphosphoric triamide (HMPT) for the reaction of allyltributyltin and α-halo ketones, furnishing the corresponding allyloxiranes in good yield; a palladium catalyst, which is generally used, is not required.

      >