Download PDF
Synlett 1990; 1990(5): 271-272
DOI: 10.1055/s-1990-21061
letter
© Georg Thieme Verlag, Rüdigerstr. 14, 70469 Stuttgart, Germany. All rights reserved. This journal, including all individual contributions and illustrations published therein, is legally protected by copyright for the duration of the copyright period. Any use, exploitation or commercialization outside the narrow limits set by copyright legislation, without the publisher's consent, is illegal and liable to criminal prosecution. This applies in particular to photostat reproduction, copying, cyclostyling, mimeographing or duplication of any kind, translating, preparation of microfilms, and electronic data processing and storage.

Elaboration of 1,2,3,4-Tetrahydroquinoline via η2-Imine complexes of Zirconocene

N. Coles* , R. J. Whitby, J. Blagg
  • *Chemistry Department, The University, Southampton S09 5NH, England
Further Information

Publication History

Publication Date:
08 March 2002 (online)

  PDF Download  Permissions and Reprints All articles of this category

1,2,3,4-Tetrahydroquinoline is converted into the zirconocene η2-imine complexes 2 or 3 via a C-H activation process. These complexes react efficiently with a range of unactivated alkenes, alkynes and allenes to afford azazircona-cyclopentanes. Workup with methanol gives the 2-substituted tetrahydroquinolines in good yield.

      >