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Synthesis 1989; 1989(3): 172-175
DOI: 10.1055/s-1989-27184
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Reactions of 2,5-Furandicarbaldehyde with Stabilized Phosphonium Ylides. Applications to the Synthesis of 5-Vinyl-2-furaldehyde and 2,5-Divinylfuran Derivatives

Carmen Domínguez* , Aurelio G. Csákÿ, Javier Magano, Joaquín Plumet
  • *Universidad Complutsense de Madrid, Facultad de Química, Departamento de Química Orgánica, Ciudad Universitaria, E-28040 Madrid, Spain
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Publication History

Publication Date:
17 September 2002 (online)

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By simple modification of the molar proportion of reactants, it was possible to selectively functionalize an aldehyde group in 2,5-furandicarbaldehyde (1), by Wittig reaction with stabilized ylides 2, The scope of the procedure is extended to the preparation of certain furancontaining natural fatty acid analogues.

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