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Synthesis 1988; 1988(11): 904-907
DOI: 10.1055/s-1988-27749
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Synthesis and Reactions of N-Alkyl-O-diphenylphosphinylhydroxylamines and N-Alkyl-N-diphenylphosphinylhydroxylamines

Guy Masse* , Georges Sturtz
  • *Laboratoire de Chimie Hétéroorganique, Faculté des Sciences et Techniques, Avenue Victor Le Gorgeu, F-29287 Brest Cedex, France
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Publication Date:
20 August 2002 (online)

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Reaction of a series of primary amines with bis(diphenylphosphinyl) peroxide conveniently leads to N-alkyl-O-diphenylphosphinylhydroxylamines. These compounds rearrange on heating to the thermodynamically more stable N-phosphinylated derivatives, the N-alkyl-N-diphenylphosphinylhydroxylamines (N-alkyldiphenylphosphinohydroxamic acids).

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