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Synthesis 1988; 1988(10): 805-806
DOI: 10.1055/s-1988-27715
DOI: 10.1055/s-1988-27715
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New Synthesis of α-Nitroso Esters and Oximes of α-Keto Esters
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Publication History
Publication Date:
12 September 2002 (online)
Ketene O-alkyl O′-silyl acetals on reaction with nitric oxide or isomayl nitrite in the presence of titanium(IV) chloride provide either one of α-nitroso esters and oximes of α-keto esters.