Synthesis 1987; 1987(10): 912-914
DOI: 10.1055/s-1987-28119
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The Bis(tricyclohexylstannyl) Sulfide Thionation of 3H-1,2,4- Triazol-3-ones

John M. Kane*
  • *Merrell Dow Research Institute, 2110 East Galbraith Road, Cincinnati, OH 45215, U.S.A.
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Publication History

Publication Date:
12 September 2002 (online)

5-Aryl-2,4-dialkyl-2,4-dihydro-3H-1,2,4-triazol-3-ones may be converted in 55-74% yield to the corresponding 3H-1,2,4-triazole-3-thiones by using the combination bis(tricyclohexylstannyl) sulfide/boron trichloride.