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Planta Med 2016; 82(16): 1438-1445
DOI: 10.1055/s-0042-110316
Natural Product Chemistry and Analytical Studies
Original Papers
Georg Thieme Verlag KG Stuttgart · New York

Phytochemical Study of Eryngium triquetrum: Isolation of Polyacetylenes and Lignans

Fouzia Bouzergoune
1   Laboratoire de Chimie et Chimie de lʼenvironnement (L. C. C. E.), Faculté des Sciences de la Matière, Département de Chimie, Université de Batna 1, Batna, Algérie
,
Maria Letizia Ciavatta
2   Consiglio Nazionale delle Ricerche (CNR), Istituto di Chimica Biomolecolare (ICB), Pozzuoli, Napoli, Italy
,
Fatma Bitam
1   Laboratoire de Chimie et Chimie de lʼenvironnement (L. C. C. E.), Faculté des Sciences de la Matière, Département de Chimie, Université de Batna 1, Batna, Algérie
3   Faculté de Médecine, Département de Pharmacie, Université de Batna 2, Batna, 05000, Algérie
,
Marianna Carbone
2   Consiglio Nazionale delle Ricerche (CNR), Istituto di Chimica Biomolecolare (ICB), Pozzuoli, Napoli, Italy
,
Mohamed Cherif Aberkane
1   Laboratoire de Chimie et Chimie de lʼenvironnement (L. C. C. E.), Faculté des Sciences de la Matière, Département de Chimie, Université de Batna 1, Batna, Algérie
,
Margherita Gavagnin
2   Consiglio Nazionale delle Ricerche (CNR), Istituto di Chimica Biomolecolare (ICB), Pozzuoli, Napoli, Italy
› Author Affiliations
Further Information

Publication History

received 18 April 2016
revised 26 May 2016

accepted 05 June 2016

Publication Date:
24 June 2016 (online)

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Abstract

Phytochemical investigation of the ethyl acetate extract from the aerial parts of Eryngium triquetrum Vahl resulted in the isolation of new polyacetylenes, triquetridiol (6) and trans-epoxy-triquetrol (7a/7b, diastereomeric mixture), and the lignan demethoxy carolignan Z (8a/8b, erythro/threo pair), together with a series of related known metabolites. Additionally, some already reported phenolic and flavonoid compounds were also identified in the extract. Structural elucidation of the new compounds was made by spectroscopic analysis, mainly NMR and mass spectrometry. To the best of our knowledge, this is the first report of polyacetylenes and lignans from E. triquetrum.

Key words

Eryngium triquetrum - Apiaceae - polyacetylenes - lignans - NMR
 

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