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CC BY-NC-ND 4.0 · Organic Materials 2020; 02(01): 020-025
DOI: 10.1055/s-0039-3402512
Short Review
The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution-NonDerivative-NonCommercial-License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes, or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by-nc-nd/4.0/). (2020) The Author(s).

Organic Molecules of Intrinsic Microporosity

Neil B. McKeown 
a   EaStCHEM School of Chemistry, University of Edinburgh, David Brewster Road, Edinburgh EH9 3FJ, United Kingdom
› Institutsangaben Funding Information The EPSRC, United Kingdom, is acknowledged for funding (EP/G065144 and EP/H024034).
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Publikationsverlauf

Received: 08. Oktober 2019

Accepted after revision: 20. November 2019

Publikationsdatum:
23. Januar 2020 (online)

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Abstract

Organic molecules of intrinsic microporosity (OMIMs) are rigid molecules with an awkward shape that are designed to pack space inefficiently in the solid state maximizing free volume and thereby generating apparent microporosity as determined by gas adsorption. In this perspective article, the origin of the OMIM concept is explained and the progress in its realization both by synthesis and packing simulation is reviewed.

Key words

Intrinsic microporosity - organic molecules - gas adsorption - packing simulations
 

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