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CC BY-NC-ND 4.0 · Organic Materials 2019; 01(01): 019-029
DOI: 10.1055/s-0039-1698431
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The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution-NonDerivative-NonCommercial-License, permitting copying and reproduction so long as the original work is given appropriate credit. Contents may not be used for commercial purposes, or adapted, remixed, transformed or built upon. (https://creativecommons.org/licenses/by-nc-nd/4.0/) (2019) The Author(s).

Fluorinated Organic Porous Materials

Zhenglin Zhang 
Department of Chemistry, University of Houston, 112 Fleming Building, Houston TX 77204-5003, USA
,
Ognjen Š. Miljanić 
Department of Chemistry, University of Houston, 112 Fleming Building, Houston TX 77204-5003, USA
› Author Affiliations Acknowledgment: Over the years, the work in our labs has been supported by the University of Houston, the National Science Foundation (DMR-1507664 and DMR-1904998), the Welch Foundation (E-1768), and the donors of the American Chemical Society Petroleum Research Fund (58919-ND4). Ognjen Š. Miljanić is a Cottrell Scholar of the Research Corporation for Science Advancement. Parts of this manuscript have been written at the Ruprecht-Karls-Universität in Heidelberg and the Alexander von Humboldt Foundation is acknowledged for supporting Ognjen Š. Miljanić's stay there.
Further Information

Publication History

Received: 20 June 2019

Accepted after revision: 24 July 2019

Publication Date:
29 November 2019 (online)

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Abstract

Fluorine is in many aspects unique among the elements, and its incorporation into organic molecules can dramatically change their physical and chemical properties. This minireview will survey the existing classes of fluorinated porous materials, with a particular focus on all-organic porous materials. We will highlight our work on the preparation and study of metal–organic frameworks and porous molecular crystals derived from extensively fluorinated rigid aromatic pyrazoles and tetrazoles. Where possible, comparisons between fluorinated and nonfluorinated materials will be made.

Key words

fluorinated molecules - porous materials - molecular crystals - macrocycles
 

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