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CC BY ND NC 4.0 · SynOpen 2017; 01(01): 0143-0146
DOI: 10.1055/s-0036-1590959
DOI: 10.1055/s-0036-1590959
letter
Ball-Milling Promoted Monobromination Reactions: One-pot Regioselective Synthesis of Aryl Bromides and α-Bromoketones by NBS and Recyclable MCM-41-SO3H at Room Temperature
Weitere Informationen
Publikationsverlauf
Received: 09. August 2017
Accepted after revision: 23. Oktober 2017
Publikationsdatum:
16. November 2017 (online)
Abstract
An effective approach to monobromination reactions utilizing room temperature ball-milling is introduced for the synthesis of aryl bromides and bromoketones with N-bromosuccinimide (NBS) and MCM-41-SO3H. Advantages of this technique are short reaction times and high regioselectivity. In contrast to other techniques using microwaves, ultrasound, or ionic liquids, handling of sensitive materials is possible and furthermore, this method has advantages over other solvent-free techniques that require a higher reaction temperature for high yield of products.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0036-1590959.
- Supporting Information
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