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Synthesis 2017; 49(21): 4775-4782
DOI: 10.1055/s-0036-1590912
DOI: 10.1055/s-0036-1590912
special topic
Developing a Bench-Scale Green Diboration Reaction toward Industrial Application
Weitere Informationen
Publikationsverlauf
Received: 12. August 2017
Accepted after revision: 28. August 2017
Publikationsdatum:
10. Oktober 2017 (online)
Dedicated to Prof. Maria Elena Fernandez and Prof. Carles Bo, our scientific parents
Published as part of the Special Topic Modern Strategies for Borylation in Synthesis
Abstract
We report a new methodology for the organocatalytic diboration reaction using inexpensive, sustainable, nontoxic, commercially available halogen salts. This is an educative manuscript for the transformation of laboratory scale reactions into a sustainable approach of appeal to industry.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/s-0036-1590912.
- Supporting Information
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For examples of the transition-metal-free activation of diboronic esters, see:
For a complete review of sp2–sp3 boryl chemistry, see:
For reviews of phase-transfer catalysis, see:
For examples of consecutive reactions using catechol diborated intermediates, see:
For some representative examples of lithiation–borylation, see: