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Synlett 2017; 28(13): 1657-1659
DOI: 10.1055/s-0036-1588794
letter
© Georg Thieme Verlag Stuttgart · New York

A Facile Synthesis of β-Iodonitro Alkenes via Iodonitration of Alkynes with tert-Butyl Nitrite and Iodine

Yuanyuan Fan
a   College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, P. R. China
,
Bei Zhou
a   College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, P. R. China
,
Kun Chen
a   College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, P. R. China
,
Bingtao Wang
b   Ningbo Institute of Technology, Zhejiang University, Ningbo 315100, P. R. China   Email: xqli@zjut.edu.cn   Email: future@zjut.edu.cn
,
Xiaoqing Li*
a   College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, P. R. China
,
Xiangsheng Xu*
a   College of Chemical Engineering, Zhejiang University of Technology, Hangzhou 310014, P. R. China
› Author AffiliationsSupported by: Natural Science Foundation of China (51503181)
Further Information

Publication History

Received: 19 March 2017

Accepted after revision: 26 March 2017

Publication Date:
27 April 2017 (online)

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Abstract

A convenient synthetic approach to β-iodonitro alkenes based on the iodonitration of alkynes with t BuONO and I2 is described. No acid or oxidant is required in this reaction.

Key words

β-iodonitro alkenes - iodonitration - alkynes - free radical - difunctionalization

Supporting Information

    Supporting information for this article is available online at https://doi.org/10.1055/s-0036-1588794.
  • Supporting Information
 

  • References and Notes

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