Merging Transition-Metal Activation and Aminocatalysis

This review is dedicated to Professor Choong Eui Song on the occasion of his 60^th birthday.

Abstract

In this review the principal enantioselective methodologies merging transition-metal catalysis and aminocatalysis are disclosed.

1 Introduction

2 Transition-Metal and Enamine Catalysis

3 Transition-Metal and Iminium Catalysis

4 Transition-Metal Catalysis and Organocascade (Iminium/Enamine) Activation

5 Conclusions and Perspectives

Key words

synergistic catalysis - multicatalysis - organocatalysis - transition-metal catalysis - cascade reactions

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