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DOI: 10.1055/s-0035-1556486
Antimalarial metabolites from Buxus sempervirens
Some malaria parasites (Plasmodium falciparum) have developed resistance to all currently available antimalarial drugs including artemisinin derivatives, so there is an urgent need to discover new chemicals with antimalarial activity. Eight new lupinane derivatives (1 – 8) were isolated from the extract of the English boxwood (Buxus sempervirens) using bioassay guided fractionation and examined for activity against malarial parasites Plasmodium falciparum. The lupinane derivatives range in potency from 0.49 – 3.36 µM against the drug sensitive HB3 parasite and retain efficacy in an artemisinin and multidrug resistant parasite recently isolated in Southeast Asia. Compounds 2 and 3 in particular exhibited greater than 30-fold selectivity for malaria parasites as compared to human cancer cell lines.
