When Chlorides are the Most Reactive: A Simple Route towards Diverse 
Mono- and Dicationic Dimethyl Phosphate Ionic Liquids

Elina Priede; Eduards Bakis; Andris Zicmanis

doi:10.1055/s-0034-1379018

Synlett, Table of Contents

Synlett 2014; 25(17): 2447-2450
DOI: 10.1055/s-0034-1379018

letter

When Chlorides are the Most Reactive: A Simple Route towards Diverse Mono- and Dicationic Dimethyl Phosphate Ionic Liquids

Elina Priede*

University of Latvia, Faculty of Chemistry, 19, Rainis Blvd., Riga, LV1586, Latvia Fax: +37167378736 Email: priede_elina@inbox.lv

,

Eduards Bakis

University of Latvia, Faculty of Chemistry, 19, Rainis Blvd., Riga, LV1586, Latvia Fax: +37167378736 Email: priede_elina@inbox.lv

,

Andris Zicmanis

University of Latvia, Faculty of Chemistry, 19, Rainis Blvd., Riga, LV1586, Latvia Fax: +37167378736 Email: priede_elina@inbox.lv

› Author Affiliations

Abstract

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Abstract

Structurally diverse aromatic and aliphatic ionic liquids have been prepared via anion metathesis utilizing alkylammonium chlorides and trimethyl phosphate. Excellent oxygen-containing functional-group tolerance in preparation of potentially greener dimethyl phosphate ionic liquids has been demonstrated. For the first time, this method has been employed in the synthesis of dicationic imidazolium-based ionic liquids possessing a dimethyl phosphate counterion, providing a simple, direct route towards structurally novel products of high purity.

Key words

monocationic ionic liquids - dicationic ionic liquids - anion metathesis - dimethyl phosphate

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References

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