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Synthesis 2014; 46(02): 263-268
DOI: 10.1055/s-0033-1340285
DOI: 10.1055/s-0033-1340285
paper
Methyl Salicylate as a Selective Methylation Agent for the Esterification of Carboxylic Acids
Authors
Weitere Informationen
Publikationsverlauf
Received: 16. August 2013
Accepted after revision: 28. Oktober 2013
Publikationsdatum:
26. November 2013 (online)
Abstract
Methyl salicylate is a selective and inexpensive methylating agent for the esterification of carboxylic acids with a wide range of functional group tolerance. The intramolecular hydrogen bonds between the carboxylate and hydroxyl groups in methyl salicylate are essential for the transformation. Allyl, benzyl, methallyl, and propargyl salicylates can also be used as alkylating agents for the preparation of the corresponding alkyl carboxylates.
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- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information (PDF)
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