Synthesis of Novel Octahedral Silicon Compounds; Synthesis of Bis[3-(1-{[aryl(hydroxy)methylene]hydrazinylidene}ethyl)-6-methyl-2-oxo-2H-pyran-4-olato-N,O,O′]silicon(IV)

Abstract

The synthesis of new silicon compounds is reported via the cyclization of dehydroacetic acid N-acylhydrazones with silicon tetraacetate. The procedure involves formation of new octahedral hexacoordinated silicon structures.

Key words

octahedral silicon - dehydroacetic acid - N-acylhydrazones - silicon tetraacetate - hypervalent silicon

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