Copper-Catalyzed Selective Single Arylsulfanylation of Aryl Diiodides with Aryl Thiols

Yunyun Liu; Hang Wang; Xiaoji Cao; Zheng Fang; Jie-Ping Wan

doi:10.1055/s-0033-1338525

Synthesis, Inhaltsverzeichnis

Synthesis 2013; 45(21): 2977-2982
DOI: 10.1055/s-0033-1338525

paper

Copper-Catalyzed Selective Single Arylsulfanylation of Aryl Diiodides with Aryl Thiols

Yunyun Liu

^aCollege of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. of China

,

Hang Wang

^aCollege of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. of China

,

Xiaoji Cao

^bResearch Centre of Analysis and Measurement, Zhejiang University of Technology, 18 Chaowang Road, Hangzhou, Zhejiang 310014, P. R. of China Fax: +86(791)88120380 eMail: wanjieping@jxnu.edu.cn

,

Zheng Fang

^aCollege of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. of China

,

Jie-Ping Wan*

^aCollege of Chemistry and Chemical Engineering, Jiangxi Normal University, Nanchang 330022, P. R. of China

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Abstract

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Abstract

Selective single arylsulfanylation reactions of aryl diiodides with aryl or hetaryl thiols to give a broad array of iodine-functionalized sulfides were developed. Further elaboration of the iodine-containing products to provide a variety of aryl and hetaryl sulfides through coupling reactions was also demonstrated.

Key words

copper - cross-coupling - iodides - sulfides - catalysis

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Referenzen

References

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16 Crystallographic data for compounds 3a and 3d have been deposited with the accession numbers CCDC 945932 and 945931, respectively, and can be obtained free of charge from the Cambridge Crystallographic Data Centre, 12 Union Road, Cambridge CB2 1EZ, UK; Fax: +44(1223)336033; E-mail: deposit@ccdc.cam.ac.uk; Web site: www.ccdc.cam.ac.uk/conts/retrieving.html.
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