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Planta Med 2012; 78 - PI291
DOI: 10.1055/s-0032-1320978
DOI: 10.1055/s-0032-1320978
Cornoside A, a new monoterpenoid glucosid with an unusual skeleton from Cornus controvers
A novel monoterpenoid glucoside with an unprecedented 2-oxabicyclo-[2.2.1]-heptan-3-one rearranged ring system was isolated from Cornus controversa and named cornoside A (1). The structure and relative stereochemistry was elucidated on the basis of extensive spectroscopic analysis. Cornoside A represents an unprecedented rearrangement iridoid. In addition, the novel compound exhibited potent LXR agonistic activity and moderate PPARγ agonistic activity.