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Synthesis 2012; 44(21): 3366-3370
DOI: 10.1055/s-0032-1317194
DOI: 10.1055/s-0032-1317194
paper
A Novel Synthesis of Thioglycolurils by Ring Contraction of 5,7-Dialkyl-3-thioxoperhydroimidazo[4,5-e]-1,2,4-triazin-6-ones
Weitere Informationen
Publikationsverlauf
Received: 24. Mai 2012
Accepted after revision: 16. August 2012
Publikationsdatum:
05. September 2012 (online)
Abstract
A new synthetic route to (E)-1,3-dialkyl-4-(benzylideneamino)-5-thioxohexahydroimidazo[4,5-d]imidazol-2(1H)-ones (thioglycolurils), by a ring contraction reaction of 5,7-dialkyl-3-thioxoperhydroimidazo[4,5-e]-1,2,4-triazin-6-ones with aromatic aldehydes, has been developed.
Key words
N-heterocycles - thioglycolurils - 3-thioxoperhydroimidazo[4,5-e]-1,2,4-triazin-6-ones - aromatic aldehydes - ring contractionSupporting Information
- for this article is available online at http://www.thieme-connect.com/ejournals/toc/synthesis.
- Supporting Information
-
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