Heck Arylation of Styrenes Promoted
by an Air-Stable Phosphinito Complex with Palladium(II); Synthesis
of Resveratrol

José Antonio Morales-Serna; Armando Zúñiga-Martínez; Manuel Salmón; Rubén Gaviño; Jorge Cárdenas

doi:10.1055/s-0031-1289664

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Synthesis 2012(3): 446-452
DOI: 10.1055/s-0031-1289664

PAPER

Heck Arylation of Styrenes Promoted by an Air-Stable Phosphinito Complex with Palladium(II); Synthesis of Resveratrol

José Antonio Morales-Serna, Armando Zúñiga-Martínez, Manuel Salmón, Rubén Gaviño, Jorge Cárdenas*
Instituto de Química, Universidad Nacional Autónoma de México Circuito Exterior, Ciudad Universitaria, Coyoacán 04510, México, D.F., México
Fax: +52(55)56162217; e-Mail: rjcp@unam.mx;

Further Information

Publication History

Received 12 September 2011
Publication Date:
03 January 2012 (online)

Abstract
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Abstract

An air-stable phosphinito complex of palladium(II) was found to be an efficient catalyst in the Heck reaction of a variety of aryl halides and styrenes. Resveratrol was concisely synthesized in 63% overall yield; the reactions were performed under conventional and microwave heating.

Key words

Heck reaction - palladium - homogeneous catalysis - halides - coupling

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