TAPC-Promoted Synthesis of
Sulfonyl Chlorides from Sulfonic Acids

Kiumars Bahrami

doi:10.1055/s-0031-1289547

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Synlett 2011(18): 2671-2674
DOI: 10.1055/s-0031-1289547

LETTER

TAPC-Promoted Synthesis of Sulfonyl Chlorides from Sulfonic Acids

Kiumars Bahrami*^a,b
^a Department of Organic Chemistry, Faculty of Chemistry, Razi University, Kermanshah 67149-67346, Iran
Fax: +98(831)4274559; e-Mail: kbahrami2@hotmail.com;
^b Nanoscience and Nanotechnology Research Center (NNRC), Razi University, Kermanshah 67149-67346, Iran

Further Information

Publication History

Received 15 August 2011
Publication Date:
19 October 2011 (online)

Abstract
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Abstract

A novel and efficient method is described for the preparation of sulfonyl chlorides from sulfonic acids using TAPC as chlorinating agent. Mild reaction conditions, shorter reaction times, high efficiencies, cost-effectiveness, and facile isolation of the desired products make the present methodology a practical alternative and will provide a valuable synthetic tool for various pharmaceutical applications.

Key words

sulfonyl chlorides - sulfonic acids - chlorinating agent - solvent-free conditions - 1,3,5-triazo-2,4,6-triphosphorine-2,2,4,4,6,6-hexachloride (TAPC)

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