Synthesis of 3-Substituted Derivatives
of 2,2,6,6-Tetramethylpiperidine-N-alkoxyamine
Ethers: Novel Alkoxyamine Building Blocks

Walter Fischer; Abdel-Ilah Basbas; Kai-Uwe Schoening; Stefan Hauck

doi:10.1055/s-0030-1258255

PAPER

Synthesis of 3-Substituted Derivatives of 2,2,6,6-Tetramethylpiperidine-N-alkoxyamine Ethers: Novel Alkoxyamine Building Blocks

Walter Fischer^a, Abdel-Ilah Basbas^a, Kai-Uwe Schoening*^a, Stefan Hauck*^b
^a BASF Schweiz AG, 4002 Basel, Switzerland
Fax: +41(61)6362115; e-Mail: kai-uwe.schoening@basf.com;
^b Galata Chemicals GmbH, 68623 Lampertheim, Germany

Abstract

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Abstract

The Michael addition of 4-oxo-TMP-alkoxyamine-derived Schiff bases to acrylates provides a convenient way to obtain a variety of novel and versatile alkoxyamine building blocks.

Key words

N-alkoxyamines - radical reaction - piperidines - peroxides - TEMPO derivatives

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