Direct Arylation of Aromatic C-H Bonds with 3Ph3P-Ru/CeO2

H. Miura; K. Wada; S. Hosokawa; M. Inoue

doi:10.1055/s-0029-1220100

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Synfacts 2010(7): 0847-0847
DOI: 10.1055/s-0029-1220100

Polymer-Supported Synthesis

Direct Arylation of Aromatic C-H Bonds with 3Ph₃P-Ru/CeO₂

Contributor(s): Yasuhiro Uozumi, Go Hamasaka
H. Miura, K. Wada*, S. Hosokawa, M. Inoue
Kyoto University, Japan

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Publication History

Publication Date:
22 June 2010 (online)

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Significance

Ph₃P-modified Ru/CeO₂ (3Ph₃P-Ru/CeO₂) was prepared by immobilization of [RuCl₂(CO)₃]₂ onto CeO₂ followed by the treatment with Ph₃P under hydrogen. The 3Ph₃P-Ru/CeO₂ composite catalyzed the direct C-H arylation of aromatic compounds 1 with aryl halides 2 to give the corresponding biaryls 3 in 53-98% isolated yield (12 examples).