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Synthesis 2009(19): 3332-3338
DOI: 10.1055/s-0029-1216948
DOI: 10.1055/s-0029-1216948
PAPER
© Georg Thieme Verlag
Stuttgart ˙ New York
One-Pot Reaction of Secondary Phosphine Selenides with Selenium and Nitrogen Bases: A Novel Synthesis of Diorganodiselenophosphinates
Weitere Informationen
Received
15 May 2009
Publikationsdatum:
21. August 2009 (online)
Publikationsverlauf
Publikationsdatum:
21. August 2009 (online)
Abstract
A three-component reaction of secondary phosphine selenides R2P(Se)H [R = PhCH2CH2, PhCH(Me)CH2, 4-t-BuC6H4CH2CH2, (2-methyl-5-pyridyl)CH2CH2, Ph], elemental selenium, and primary, secondary, and tertiary amines and diamines proceeds under mild conditions (25-85 ˚C, 1-90 min) in tetrahydrofuran-ethanol as medium to give previously unknown mono-, di-, and triorganoammonium salts of diorganodiselenophosphinates in high yields (up to 99%).
Key words
secondary phosphine selenides - elemental selenium - amines - three-component atom-economic reactions - diselenophosphinates - phosphorus compounds
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