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Synthesis
DOI: 10.1055/a-2615-1768
DOI: 10.1055/a-2615-1768
paper
Romanian Chemists in Synthesis
Carbon–Carbon Bond Formation Mediated by an Iron(0)–Olefin Pincer Complex
This work was supported by the National Science Foundation grant CAS-2102517 (VMI). Crystallographic data was collected on a diffractometer acquired with the help of the National Science Foundation grant MRI award CHE-2214606.
Abstract
C–H functionalization is a highly appealing strategy for accessing complex molecular structures. Herein, we show that π-tethered pincer ligands can engage in C–H activation when coordinated to iron. These reactions result in C(sp2)–C(sp2) bond formation through oxidative coupling and β-hydride elimination/reductive elimination pathways with alkynes and isocyanides.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2615-1768.
- Supporting Information
- CIF File
Publikationsverlauf
Eingereicht: 28. März 2025
Angenommen nach Revision: 16. Mai 2025
Accepted Manuscript online:
16. Mai 2025
Artikel online veröffentlicht:
17. Juni 2025
© 2025. Thieme. All rights reserved
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