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CC BY 4.0 · Sustainability & Circularity NOW 2024; 01: a24217430
DOI: 10.1055/a-2421-7430
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Solvent-Free Approaches for the Synthesis of Lophine Derivatives

Authors

  • Shiv R. Desai 

    1   Laboratory of Organic Chemistry, Tarsadia Institute of Chemical Science, Uka Tarsadia University, Maliba Campus, Gopal Vidyanagar, Bardoli-Mahuva Road, Tarsadi, 394350 Surat, Gujarat, India

  • Sachin G. Modha 

    1   Laboratory of Organic Chemistry, Tarsadia Institute of Chemical Science, Uka Tarsadia University, Maliba Campus, Gopal Vidyanagar, Bardoli-Mahuva Road, Tarsadi, 394350 Surat, Gujarat, India
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Abstract

Solvent-free synthesis comes with many advantages such as cost reduction, waste reduction, ease of operation, sustainability, environmentally benign operations, etc. These benefits have prompted many chemists to develop new protocols for solvent-free synthesis of various interesting chemical compounds. One such class of compounds is 2,4,5-triarylimidazoles, commonly known as lophines due to their applications in materials science, chemo- and bio-sensors, and pharmacology. This article focuses on solvent-free synthesis of lophine derivatives via different protocols, including the use of inorganic-, organic-, and biocatalysts; solid-supported catalysts; microwave-mediated heating; and grinding.

Keywords

Lophine - Triaryl imidazoles - Imidazoles - Solvent-free - Neat - Sustainable chemistry - Green chemistry - Multicomponent reactions


Publication History

Received: 18 July 2024

Accepted after revision: 20 September 2024

Accepted Manuscript online:
27 September 2024

Article published online:
11 November 2024

© 2024. The Author(s). This is an open access article published by Thieme under the terms of the Creative Commons Attribution License, permitting unrestricted use, distribution, and reproduction so long as the original work is properly cited. (https://creativecommons.org/licenses/by/4.0/).

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Bibliographical Record
Shiv R. Desai, Sachin G. Modha. Solvent-Free Approaches for the Synthesis of Lophine Derivatives. Sustainability & Circularity NOW 2024; 01: a24217430.
DOI: 10.1055/a-2421-7430
 

  • References

  • 1 Anastas P, Eghbali N. Chem. Soc. Rev. 2010; 39: 301
    Search in Google Scholar
    • 2a Anastas PT, Kirchhoff MM. Acc. Chem. Res. 2002; 35: 686
      Search in Google Scholar
    • 2b Anastas PT, Beach ES. Green Chem. Lett. Rev. 2007; 1: 9
      Search in Google Scholar
    • 2c Kreuder AD, House-Knight T, Whitford J, Ponnusamy E, Miller P, Jesse N, Rodenborn R, Sayag S, Gebel M, Aped I, Sharfstein I, Manaster E, Ergaz I, Harris A, Grice LN. ACS Sustainable Chem. Eng. 2017; 5: 2927
      Search in Google Scholar
    • 2d Federsel H.-J. Synthesis 2022; 54: 4257
      Search in Google Scholar
  • 3 Clarke CJ, Tu W.-C, Levers O, Bröhl A, Hallett JP. Chem. Rev. 2018; 118: 747
    Search in Google Scholar
    • 5a Martins MA. P, Frizzo CP, Moreira DN, Buriol L, Machado P. Chem. Rev. 2009; 109: 4140
      Search in Google Scholar
    • 5b Singh MS, Chowdhury S. RSC Adv. 2012; 2: 4547
      Search in Google Scholar
    • 5c Obst M, König B. Eur. J.Org. Chem. 2018; 2018: 4213
      Search in Google Scholar
    • 5d Sarkar A, Santra S, Kundu SK, Hajra A, Zyryanov GV, Chupakhin ON, Charushin VN, Majee A. Green Chem. 2016; 18: 4475
      Search in Google Scholar
  • 6 Desai SR, Bhoraniya RB, Koladiya M, Bhopekar VV, Patel CR, Mori T, Modha SG. J. Photochem. Photobiol., A 2024; 455: 115751
    Search in Google Scholar
    • 7a Kimura M, Tsunenaga M, Takami S, Ohbayashi Y. Bull. Chem. Soc. Jpn. 2005; 78: 929
      Search in Google Scholar
    • 7b Dietz MS, Wehrheim SS, Harwardt M.-LI. E, Niemann HH, Heilemann M. Nano Lett. 2019; 19: 8245
      Search in Google Scholar
    • 7c Wang Y, Qiu D, Li M, Liu Y, Chen H, Li H. Spectrochim. Acta, Part A 2017; 185: 256
      Search in Google Scholar
    • 7d Wang Y, Liu S, Chen H, Liu Y, Li H. Dyes Pigm. 2017; 142: 293
      Search in Google Scholar
  • 8 Gangadhar PS, Jagadeesh A, Rajesh MN, George AS, Prasanthkumar S, Soman S, Giribabu L. Mater. Adv. 2022; 3: 1231
    Search in Google Scholar
  • 9 Zhou Z, Ding Y, Si S, Wu W, Deng C, Wu H, Xiang J. J. Hazard. Mater. 2021; 417: 125975
    Search in Google Scholar
  • 10 Akamatsu MJ. Jpn. Soc. Colour Mater. 2020; 93: 210
    Search in Google Scholar
    • 11a Zhang Z, Lai J, Wu K, Huang X, Guo S, Zhang L, Liu J. Talanta 2018; 180: 260
      Search in Google Scholar
    • 11b Yamaguchi S, Kishikawa N, Ohyama K, Ohba Y, Kohno M, Masuda T, Takadate A, Nakashima K, Kuroda N. Anal. Chim. Acta 2010; 665: 74
      Search in Google Scholar
    • 11c Pavlova E, Kaloyanova S, Deligeorgiev T, Lesev N. Eur. Biophys. 2015; 44: 623
      Search in Google Scholar
    • 12a Singh AK, Zhu Y, Han M, Huang H. Smart Mater. Struct. 2016; 25: 115019
      Search in Google Scholar
    • 12b Yoo WJ, Seo JK, Jang KW, Heo JY, Moon JS, Park J.-Y, Park BG, Lee B. Opt. Rev. 2011; 18: 132
      Search in Google Scholar
  • 13 Bhattacharyya P, Medda A, Samanta A, Guchhait N, Das AR. ChemInform 2012; 43: 983
    Search in Google Scholar
  • 14 Zhao YS, Xiao D, Yang W, Peng A, Yao J. Chem. Mater. 2006; 18: 2302
    Search in Google Scholar
  • 15 Saxer S, Marestin C, Mercier R, Dupuy J. Polym. Chem. 2018; 9: 1927
    Search in Google Scholar
  • 16 Karimi-Jaberi Z, Barekat M. Chin. Chem. Lett. 2010; 21: 1183
    Search in Google Scholar
  • 17 Esmaeilpour M, Javidi J, Dehghani F, Zahmatkesh S. Res. Chem. Intermed. 2017; 43: 163
    Search in Google Scholar
  • 18 Gajengi AL, Chaurasia S, Monflier E, Ponchel A, Ternel J, Bhanage BM. Catal. Commun. 2021; 161: 106366
    Search in Google Scholar
  • 19 Yar M, Bajda M, Shahzad S, Ullah N, Gilani MA, Ashraf M, Rauf A, Shaukat A. Bioorg. Chem. 2015; 58: 65
    Search in Google Scholar
  • 20 Pervaiz S, Mutahir S, Ullah I, Ashraf M, Liu X, Tariq S, Zhou BJ, Khan MA. Chem. Biodiversity 2020; 17: e1900493
    Search in Google Scholar
  • 21 Ghogare RS. Org. Commun. 2022; 15: 44
    Search in Google Scholar
  • 22 Maleki A, Paydar R. RSC Adv. 2015; 5: 33177
    Search in Google Scholar
  • 23 Tamuli KJ, Dutta D, Nath S, Bordoloi M. ChemistrySelect 2017; 2: 7787
    Search in Google Scholar
  • 24 Girish YR, Kumar KS. S, Thimmaiah KN, Rangappa KS, Shashikanth S. RSC Adv. 2015; 5: 75533
    Search in Google Scholar
  • 25 Fekri LZ, Nikpassand M, Shariati S, Aghazadeh B, Zarkeshvari R, Pour N. N. J. Organomet. Chem. 2018; 871: 60
    Search in Google Scholar
  • 26 Manteghi F, Zakeri F, Guy OJ, Tehrani Z. Nanomaterials 2021; 11: 845
    Search in Google Scholar
  • 27 Wang D, Li Z, Huang X, Li Y. ChemistrySelect 2016; 1: 664
    Search in Google Scholar
  • 28 Mirzaee MR, Saberi S. Chin. J. Chem. 2010; 28: 663
    Search in Google Scholar
  • 29 Mahdavinia GH, Amani AM, Sepehrian H. Chin. J. Chem. 2012; 30: 703
    Search in Google Scholar
  • 30 Ghorbani-Choghamarani A, Ghorbani F, Yousofvand Z, Azadi G. J. Porous Mater. 2015; 22: 665
    Search in Google Scholar
  • 31 Salimi M, Nasseri MA, Chapesshloo TD, Zakerinasab B. RSC Adv. 2015; 5: 33974
    Search in Google Scholar
  • 32 Mirsafaei R, Heravi MM, Ahmadi S, Hosseinnejad T. Chem. Pap. 2016; 70: 418
    Search in Google Scholar
  • 33 Borhade AV, Tope DR, Gite SG. Arab. J. Chem. 2017; 10: S559
    Search in Google Scholar
  • 34 Xu X, Li Y. Res. Chem. Intermed. 2015; 41: 4169
    Search in Google Scholar
  • 35 Chavan LD, Shankarwar SG. Cuihua Xuebao/Chin. J. Catal. 2015; 36: 1054
    Search in Google Scholar
  • 36 Maleki B, Eshghi H, Khojastehnezhad A, Tayebee R, Ashrafi SS, Kahoo GE, Moeinpour F. RSC Adv. 2015; 5: 64850
    Search in Google Scholar
  • 37 Dipake SS, Lande MK, Rajbhoj AS, Gaikwad ST. Res. Chem. Intermed. 2021; 47: 2245
    Search in Google Scholar
  • 38 Rabiei K, Pouramiri B, Neshati M, Imanvand A. J. Organomet. Chem. 2023; 1001: 122888
    Search in Google Scholar
  • 39 Gholap DP, Huse R, Dipake S, Lande MK. RSC Adv. 2023; 13: 2090
    Search in Google Scholar
  • 40 Banothu J, Gali R, Velpula R, Bavantula R. Arab. J. Chem. 2017; 10: S2754
    Search in Google Scholar
  • 41 Patel G, Patel AR, Banerjee S. New J. Chem. 2020; 44: 13295
    Search in Google Scholar
  • 42 Zhou JF, Gong GX, Sun XJ, Zhu YL. Synth. Commun. 2010; 40: 1134
    Search in Google Scholar
  • 43 Esmaeilpour M, Javidi J, Zandi M. New J. Chem. 2015; 39: 3388
    Search in Google Scholar
  • 44 Naeimi H, Aghaseyedkarimi D. New J. Chem. 2015; 39: 9415
    Search in Google Scholar
  • 45 Tambe A, Gadhave A, Pathare A, Shirole G. Sustainable Chem.Pharm. 2021; 22: 100485
    Search in Google Scholar
  • 46 Patil S, Patil J, Dharap S. World J. Pharm. Res. 2015; 4: 2476
    Search in Google Scholar
  • 47 Pradhan K, Tiwary BK, Hossain M, Chakraborty R, Nanda AK. RSC Adv. 2016; 6: 10743
    Search in Google Scholar
  • 48 Asressu KH, Chan CK, Wang CC. RSC Adv. 2021; 11: 28061
    Search in Google Scholar
  • 49 Bhukta S, Chatterjee R, Dandela R. Synthesis 2022; 55: 846
    Search in Google Scholar