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DOI: 10.1055/a-2261-3255
Visible-Light-Driven Oxidative Chlorination of Alkyl sp3 C–H Bonds with HCl/Air at Room Temperature
Abstract
An aerobic chlorination of alkyl sp3 C–H bonds of functionalized alkanes and simple alkanes has been established successfully under visible light at room temperature. The reaction is performed in the presence of catalytic NaNO2 using HCl or NaCl/acid as a chlorine source and air as a terminal oxidant under atmospheric pressure. It is suggested that NOCl from NaNO2/HCl is a crucial species in the catalytic cycle involving an aerobic oxidation and a photochemical radical chlorination.
Supporting Information
- Supporting information for this article is available online at https://doi.org/10.1055/a-2261-3255.
- Supporting Information
Publication History
Received: 16 December 2023
Accepted after revision: 05 February 2024
Accepted Manuscript online:
05 February 2024
Article published online:
26 February 2024
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